Visible-light promoted γ-cyanoalkyl radical generation: three-component cyanopropylation/etherification of unactivated alkenes

A photoredox approach to generate distal cyano-substituted alkyl radicals through C-C bond cleavage of cyclobutanone oximes was developed. The radicals produced by this method were applied to three-component cyanopropylation/etherification of unactivated alkenes. Their reactions with diverse radical...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-10, Vol.53 (84), p.11544-11547
Hauptverfasser: Li, Linyong, Chen, Haoguo, Mei, Mingjing, Zhou, Lei
Format: Artikel
Sprache:eng
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