Catalytic Asymmetric [8+2] Annulation Reactions Promoted by a Recyclable Immobilized Isothiourea

Higher‐order cycloaddition reactions constitute an efficient approach towards the construction of medium to large ring systems. However, enantioselective versions of these transformations remain scarce, which hampers their deployment in medicinal chemistry, or any other discipline in which homochira...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-11, Vol.56 (47), p.15068-15072
Hauptverfasser:	Wang, Shoulei, Rodríguez‐Escrich, Carles, Pericàs, Miquel A.
Format:	Artikel
Sprache:	eng
Schlagworte:	[8+2] cycloaddition Ammonium asymmetric catalysis Carboxylic acids Catalysis Chemical reactions Cycloaddition Enantiomers higher-order cycloaddition reactions immobilized catalysts isothioureas Organic chemistry Polycyclic compounds
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