Semiconductive Copper(I)–Organic Frameworks for Efficient Light‐Driven Hydrogen Generation Without Additional Photosensitizers and Cocatalysts

As the first example of a photocatalytic system for splitting water without additional cocatalysts and photosensitizers, the comparatively cost‐effective Cu2I2‐based MOF, Cu‐I‐bpy (bpy=4,4′‐bipyridine) exhibited highly efficient photocatalytic hydrogen production (7.09 mmol g−1 h−1). Density functio...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-11, Vol.56 (46), p.14637-14641
Hauptverfasser:	Shi, Dongying, Zheng, Rui, Sun, Ming‐Jun, Cao, Xinrui, Sun, Chun‐Xiao, Cui, Chao‐Jie, Liu, Chun‐Sen, Zhao, Junwei, Du, Miao
Format:	Artikel
Sprache:	eng
Schlagworte:	Copper copper(I) halides Density functional theory Hydrogen Hydrogen evolution hydrogen generation Hydrogen production Hydrogen storage metal–organic frameworks Photocatalysis semiconductors Splitting
Online-Zugang:	Volltext
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