Thermal and crystallization studies of nano-hydroxyapatite reinforced polyamide 66 biocomposites

The thermal and crystalline behaviour of nano-hydroxyapatite (n-HA) reinforced polyamide 66 (PA66) biocomposites was studied by thermogravimetry (TG) and differential scanning calorimetry (DSC). The thermal properties of PA66 and n-HA/PA66 composites were analysed by TG. The effect of hydroxyapatite on the melting and crystallization of PA66 was evaluated by DSC. DSC measurements exhibited an increase in the crystallization temperature, however, decrease in crystallinity with the addition of n-HA to the PA66 matrix, which was attributed to the hydrogen bonds between the n-HA surface and polyamide 66 molecules. With increase of n-HA content, the melting peak of the PA66 component shifted to higher temperature, suggesting constrained melting. The addition of n-HA to PA66 played the role of nucleating agent and enhanced the crystallization rate. Non-isothermal parameter a measured by Liu method varies from 1.13 to 1.18, from 1.02 to 1.07, and from 1.18 to 1.21 for PA66, 30 wt% n-HA/PA66 and 40 wt% n-HA/PA66, respectively, and the values of K ( T) systematically increase with rise in relative degree of crystallinity.