Salen(Co(iii)) imprisoned within pores of a metal-organic framework by post-synthetic modification and its asymmetric catalysis for CO2 fixation at room temperature

Herein, a new preparation strategy of chiral metal-organic frameworks (CMOFs) has been demonstrated. By adsorption and then post-synthetically modified (PSM) procedures, chiral salen(Co(iii)) could be imprisoned within the cages of an MOF and remained in its free form. This is the first report on th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-10, Vol.53 (79), p.10930-10933
Hauptverfasser: Chen, Danping, Luo, Ran, Li, Meiyan, Wen, Mengqi, Li, Yan, Chen, Chao, Zhang, Ning
Format: Artikel
Sprache:eng
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