Salen(Co(iii)) imprisoned within pores of a metal-organic framework by post-synthetic modification and its asymmetric catalysis for CO2 fixation at room temperature

Salen(Co(iii)) imprisoned within pores of a metal-organic framework by post-synthetic modification and its asymmetric catalysis for CO2 fixation at room temperature

Herein, a new preparation strategy of chiral metal-organic frameworks (CMOFs) has been demonstrated. By adsorption and then post-synthetically modified (PSM) procedures, chiral salen(Co(iii)) could be imprisoned within the cages of an MOF and remained in its free form. This is the first report on th...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-10, Vol.53 (79), p.10930-10933
Hauptverfasser: Chen, Danping, Luo, Ran, Li, Meiyan, Wen, Mengqi, Li, Yan, Chen, Chao, Zhang, Ning
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container_start_page 10930
container_title Chemical communications (Cambridge, England)
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creator Chen, Danping
Luo, Ran
Li, Meiyan
Wen, Mengqi
Li, Yan
Chen, Chao
Zhang, Ning
description Herein, a new preparation strategy of chiral metal-organic frameworks (CMOFs) has been demonstrated. By adsorption and then post-synthetically modified (PSM) procedures, chiral salen(Co(iii)) could be imprisoned within the cages of an MOF and remained in its free form. This is the first report on the successful application of CMOFs in heterogeneous asymmetric catalysis for coupling CO2 with epoxides to obtain optically active cyclic carbonates at room temperature.
doi_str_mv 10.1039/c7cc06522a
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title Salen(Co(iii)) imprisoned within pores of a metal-organic framework by post-synthetic modification and its asymmetric catalysis for CO2 fixation at room temperature
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