Transport of lead and diesel fuel through a peat soil near Juneau, AK: a pilot study

A set of peat column experiments was used to determine the transport potential of lead (Pb) and diesel range organics (DRO) in palustrine slope wetlands near Juneau, AK. This project is important to southeast Alaskan communities because limited land resources are forcing development of regional wetl...

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Veröffentlicht in:Journal of contaminant hydrology 2004-10, Vol.74 (1-4), p.1-18
Hauptverfasser: Deiss, Julian, Byers, Carl, Clover, Dave, D'Amore, Dave, Love, Alan, Menzies, Malcolm A., Powell, Jim, Todd Walter, M.
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container_end_page 18
container_issue 1-4
container_start_page 1
container_title Journal of contaminant hydrology
container_volume 74
creator Deiss, Julian
Byers, Carl
Clover, Dave
D'Amore, Dave
Love, Alan
Menzies, Malcolm A.
Powell, Jim
Todd Walter, M.
description A set of peat column experiments was used to determine the transport potential of lead (Pb) and diesel range organics (DRO) in palustrine slope wetlands near Juneau, AK. This project is important to southeast Alaskan communities because limited land resources are forcing development of regional wetlands. This study was instigated by concerns that proposed modifications to a nearby rifle range using DRO-contaminated soil posed a potential risk to an anadromous fish-bearing stream 250 m from the site. Three pairs of peat columns were extracted from the rifle range for analysis, one pair along and two pairs across the natural bedding planes of the soil. One column in each pair was spiked with Pb and DRO and the other was used as a control. Approximately 1-year worth of water (171 cm) was passed through each column and leachate was collected at regular intervals. The results showed that substantial DRO transport only occurred along the bedding planes. Leads was surprisingly mobile, both along and across the bedding planes with estimated soil–water partition coefficients several orders of magnitude lower than commonly published values, probably because the peat was heavily Pb-loaded by lead from bullets and because the peat's acidic, organic-rich environment enhanced Pb mobility. The chemical outflow behavior agreed with a simple macropore transport model. These results underscore the need for caution when developing regional wetlands.
doi_str_mv 10.1016/j.jconhyd.2004.02.003
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This project is important to southeast Alaskan communities because limited land resources are forcing development of regional wetlands. This study was instigated by concerns that proposed modifications to a nearby rifle range using DRO-contaminated soil posed a potential risk to an anadromous fish-bearing stream 250 m from the site. Three pairs of peat columns were extracted from the rifle range for analysis, one pair along and two pairs across the natural bedding planes of the soil. One column in each pair was spiked with Pb and DRO and the other was used as a control. Approximately 1-year worth of water (171 cm) was passed through each column and leachate was collected at regular intervals. The results showed that substantial DRO transport only occurred along the bedding planes. Leads was surprisingly mobile, both along and across the bedding planes with estimated soil–water partition coefficients several orders of magnitude lower than commonly published values, probably because the peat was heavily Pb-loaded by lead from bullets and because the peat's acidic, organic-rich environment enhanced Pb mobility. The chemical outflow behavior agreed with a simple macropore transport model. 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Leads was surprisingly mobile, both along and across the bedding planes with estimated soil–water partition coefficients several orders of magnitude lower than commonly published values, probably because the peat was heavily Pb-loaded by lead from bullets and because the peat's acidic, organic-rich environment enhanced Pb mobility. The chemical outflow behavior agreed with a simple macropore transport model. These results underscore the need for caution when developing regional wetlands.</description><subject>Absorption</subject><subject>Alaska</subject><subject>Animal and plant ecology</subject><subject>Animal, plant and microbial ecology</subject><subject>Animals</subject><subject>Biological and medical sciences</subject><subject>Contaminant transport</subject><subject>diesel fuel</subject><subject>Diesel range organic (DRO)</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Engineering and environment geology. 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This project is important to southeast Alaskan communities because limited land resources are forcing development of regional wetlands. This study was instigated by concerns that proposed modifications to a nearby rifle range using DRO-contaminated soil posed a potential risk to an anadromous fish-bearing stream 250 m from the site. Three pairs of peat columns were extracted from the rifle range for analysis, one pair along and two pairs across the natural bedding planes of the soil. One column in each pair was spiked with Pb and DRO and the other was used as a control. Approximately 1-year worth of water (171 cm) was passed through each column and leachate was collected at regular intervals. The results showed that substantial DRO transport only occurred along the bedding planes. Leads was surprisingly mobile, both along and across the bedding planes with estimated soil–water partition coefficients several orders of magnitude lower than commonly published values, probably because the peat was heavily Pb-loaded by lead from bullets and because the peat's acidic, organic-rich environment enhanced Pb mobility. The chemical outflow behavior agreed with a simple macropore transport model. These results underscore the need for caution when developing regional wetlands.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>15358484</pmid><doi>10.1016/j.jconhyd.2004.02.003</doi><tpages>18</tpages></addata></record>
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subjects Absorption
Alaska
Animal and plant ecology
Animal, plant and microbial ecology
Animals
Biological and medical sciences
Contaminant transport
diesel fuel
Diesel range organic (DRO)
Earth sciences
Earth, ocean, space
Engineering and environment geology. Geothermics
Environmental Monitoring - instrumentation
Environmental Monitoring - methods
Exact sciences and technology
Fishes
Fresh water ecosystems
Fundamental and applied biological sciences. Psychology
Gasoline - analysis
Hydrology
Hydrology. Hydrogeology
leaching
lead
Lead (Pb)
Lead - analysis
lead shot
Macropore
Models, Biological
Peat
peat soils
Pilot Projects
polluted soils
Pollution, environment geology
Rifle range
rifle ranges
Risk Assessment
shooting ranges
Soil Pollutants - analysis
soil pollution
soil transport processes
spent shot
Synecology
Time Factors
Water Movements
Water Pollutants - analysis
Wetland
wetland soils
title Transport of lead and diesel fuel through a peat soil near Juneau, AK: a pilot study
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