Radical-Enhanced Acidity: Why Bicarbonate, Carboxyl, Hydroperoxyl, and Related Radicals Are So Acidic

Comparison of accepted pK a values of bicarbonate, carboxyl, and hydroperoxyl radicals, with those of models having the unpaired electron replaced by H atoms, implied the acidity of the radicals was greatly increased. A Density Functional Theory computational method of estimating pK as was developed...

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Veröffentlicht in:	The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2017-10, Vol.121 (40), p.7761-7767
1. Verfasser:	Walton, John C
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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