Combination of Lewis Basic Selenium Catalysis and Redox Selenium Chemistry: Synthesis of Trifluoromethylthiolated Tertiary Alcohols with Alkenes

A new and efficient method for diaryl selenide catalyzed vicinal CF3S hydroxylation of 1,1-multisubstitued alkenes has been developed. Various trifluoromethylthiolated tertiary alcohols could be readily synthesized under mild conditions. This method is also effective for the intramolecular cyclizati...

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Veröffentlicht in:	Organic letters 2017-09, Vol.19 (18), p.4940-4943
Hauptverfasser:	Zhu, Zechen, Luo, Jie, Zhao, Xiaodan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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