Solvate and protic ionic liquids from aza-crown ethers: synthesis, thermal properties, and LCST behavior

In recent years, solvate and protic ionic liquids (ILs) have attracted much attention. We synthesized both types of ILs from alkyl aza-crown ethers (L = N-propyl-1-aza-15-crown-5 (L ) and N-C F C H -1-aza-15-crown-5 (L )). The solvate ILs [ML][Tf N] (M = Na , K ) were solids (T = 58-68 °C), whereas...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2018-01, Vol.20 (5), p.3118-3127
Hauptverfasser:	Oba, Yukiko, Okuhata, Megumi, Osakai, Toshiyuki, Mochida, Tomoyuki
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Basicity Cations Crown ethers Crystal structure Ethers Glass transition temperature Ionic liquids Ions Melting points Synthesis Temperature Thermodynamic properties
Online-Zugang:	Volltext
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