UV-Induced Hydrogen-Atom-Transfer Processes in 3‑Thio-1,2,4-triazole Isolated in Ar and H2 Low-Temperature Matrixes

The UV-induced thione → thiol phototautomeric reaction has been studied for monomeric 3-thio-1,2,4-triazole (3-ST) isolated in low-temperature Ar and n-H2 (normal hydrogen) matrixes. Prior to any UV irradiation, monomers of 3-ST isolated in solid Ar or solid n-H2 adopted mainly the most stable thion...

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Veröffentlicht in:The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Molecules, spectroscopy, kinetics, environment, & general theory, 2017-09, Vol.121 (37), p.6932-6941
Hauptverfasser: Rostkowska, Hanna, Lapinski, Leszek, Nowak, Maciej J
Format: Artikel
Sprache:eng
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