Valence Interconversion of Octahedral Nickel(II/III/IV) Centers
Three oxidation states (+2, +3, +4) of an octahedral nickel center were stabilized in a newly prepared RhNiRh trinuclear complex, [Ni{Rh(apt)3}2]n+ (apt=3‐ aminopropanethiolate), in which the nickel center was bound by six thiolato donors sourced from two redox‐inert fac‐[RhIII(apt)3] octahedral uni...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2017-10, Vol.56 (44), p.13762-13766 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Kouno, Masahiro Yoshinari, Nobuto Kuwamura, Naoto Yamagami, Kohei Sekiyama, Akira Okumura, Mitsutaka Konno, Takumi |
| description | Three oxidation states (+2, +3, +4) of an octahedral nickel center were stabilized in a newly prepared RhNiRh trinuclear complex, [Ni{Rh(apt)3}2]n+ (apt=3‐ aminopropanethiolate), in which the nickel center was bound by six thiolato donors sourced from two redox‐inert fac‐[RhIII(apt)3] octahedral units. The three oxidation states of the octahedral nickel center were fully characterized by single‐crystal X‐ray crystallography, as well as spectroscopic, electrochemical, and magnetic measurements; all three were interconvertible, and the conversion was accompanied by changes in color, magnetism, and Jahn–Teller distortion.
Bridge over troubled water: A series of S‐bridged RhNiRh trinuclear complexes capable of supporting an octahedral nickel center in three different oxidation states (+2, +3, +4) have been isolated. Oxidation state interconversion is accompanied by changes in color, magnetism, and geometric Jahn–Teller distortions, with retention of the trinuclear structure. |
| doi_str_mv | 10.1002/anie.201708169 |
| format | Article |
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Bridge over troubled water: A series of S‐bridged RhNiRh trinuclear complexes capable of supporting an octahedral nickel center in three different oxidation states (+2, +3, +4) have been isolated. Oxidation state interconversion is accompanied by changes in color, magnetism, and geometric Jahn–Teller distortions, with retention of the trinuclear structure.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201708169</identifier><identifier>PMID: 28846211</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Crystallography ; Electrochemistry ; high oxidation states ; Magnetic measurement ; Magnetism ; Nickel ; Oxidation ; redox chemistry ; Single crystals ; sulfur ligands ; X-ray crystallography</subject><ispartof>Angewandte Chemie International Edition, 2017-10, Vol.56 (44), p.13762-13766</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4769-b88051bc8f42f2413be3d8817eb1e930b340e0cc9fd39f83bbf21c6ed996477a3</citedby><cites>FETCH-LOGICAL-c4769-b88051bc8f42f2413be3d8817eb1e930b340e0cc9fd39f83bbf21c6ed996477a3</cites><orcidid>0000-0003-2457-0967 ; 0000-0003-4612-5418 ; 0000-0002-3684-0357 ; 0000-0001-5957-2693</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201708169$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201708169$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,45579,45580</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28846211$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kouno, Masahiro</creatorcontrib><creatorcontrib>Yoshinari, Nobuto</creatorcontrib><creatorcontrib>Kuwamura, Naoto</creatorcontrib><creatorcontrib>Yamagami, Kohei</creatorcontrib><creatorcontrib>Sekiyama, Akira</creatorcontrib><creatorcontrib>Okumura, Mitsutaka</creatorcontrib><creatorcontrib>Konno, Takumi</creatorcontrib><title>Valence Interconversion of Octahedral Nickel(II/III/IV) Centers</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>Three oxidation states (+2, +3, +4) of an octahedral nickel center were stabilized in a newly prepared RhNiRh trinuclear complex, [Ni{Rh(apt)3}2]n+ (apt=3‐ aminopropanethiolate), in which the nickel center was bound by six thiolato donors sourced from two redox‐inert fac‐[RhIII(apt)3] octahedral units. The three oxidation states of the octahedral nickel center were fully characterized by single‐crystal X‐ray crystallography, as well as spectroscopic, electrochemical, and magnetic measurements; all three were interconvertible, and the conversion was accompanied by changes in color, magnetism, and Jahn–Teller distortion.
Bridge over troubled water: A series of S‐bridged RhNiRh trinuclear complexes capable of supporting an octahedral nickel center in three different oxidation states (+2, +3, +4) have been isolated. Oxidation state interconversion is accompanied by changes in color, magnetism, and geometric Jahn–Teller distortions, with retention of the trinuclear structure.</description><subject>Crystallography</subject><subject>Electrochemistry</subject><subject>high oxidation states</subject><subject>Magnetic measurement</subject><subject>Magnetism</subject><subject>Nickel</subject><subject>Oxidation</subject><subject>redox chemistry</subject><subject>Single crystals</subject><subject>sulfur ligands</subject><subject>X-ray crystallography</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqF0MFPwjAUBvDGaATRq0ezxAseBn3ttrYnQwjqEgIX5bps3Vscjg1bpuG_twuoiRcPzevh9742HyHXQEdAKRundYkjRkFQCZE6IX0IGfhcCH7q7gHnvpAh9MiFtWvnpaTROem5GUQMoE_uV2mFtUYvrndodFN_oLFlU3tN4S31Ln3F3KSVtyj1G1bDOB7H3VndeVPsFuwlOSvSyuLVcQ7Iy8Psefrkz5eP8XQy93UgIuVn7uEQMi2LgBUsAJ4hz6UEgRmg4jTjAUWqtSpyrgrJs6xgoCPMlYoCIVI-IMND7tY07y3aXbIprcaqSmtsWpuA4pxxACocvf1D101ravc7p0KQUcgkc2p0UNo01hoskq0pN6nZJ0CTrtqkqzb5qdYt3Bxj22yD-Q__7tIBdQCfZYX7f-KSySKe_YZ_ATJVgrs</recordid><startdate>20171023</startdate><enddate>20171023</enddate><creator>Kouno, Masahiro</creator><creator>Yoshinari, Nobuto</creator><creator>Kuwamura, Naoto</creator><creator>Yamagami, Kohei</creator><creator>Sekiyama, Akira</creator><creator>Okumura, Mitsutaka</creator><creator>Konno, Takumi</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2457-0967</orcidid><orcidid>https://orcid.org/0000-0003-4612-5418</orcidid><orcidid>https://orcid.org/0000-0002-3684-0357</orcidid><orcidid>https://orcid.org/0000-0001-5957-2693</orcidid></search><sort><creationdate>20171023</creationdate><title>Valence Interconversion of Octahedral Nickel(II/III/IV) Centers</title><author>Kouno, Masahiro ; Yoshinari, Nobuto ; Kuwamura, Naoto ; Yamagami, Kohei ; Sekiyama, Akira ; Okumura, Mitsutaka ; Konno, Takumi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4769-b88051bc8f42f2413be3d8817eb1e930b340e0cc9fd39f83bbf21c6ed996477a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Crystallography</topic><topic>Electrochemistry</topic><topic>high oxidation states</topic><topic>Magnetic measurement</topic><topic>Magnetism</topic><topic>Nickel</topic><topic>Oxidation</topic><topic>redox chemistry</topic><topic>Single crystals</topic><topic>sulfur ligands</topic><topic>X-ray crystallography</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kouno, Masahiro</creatorcontrib><creatorcontrib>Yoshinari, Nobuto</creatorcontrib><creatorcontrib>Kuwamura, Naoto</creatorcontrib><creatorcontrib>Yamagami, Kohei</creatorcontrib><creatorcontrib>Sekiyama, Akira</creatorcontrib><creatorcontrib>Okumura, Mitsutaka</creatorcontrib><creatorcontrib>Konno, Takumi</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kouno, Masahiro</au><au>Yoshinari, Nobuto</au><au>Kuwamura, Naoto</au><au>Yamagami, Kohei</au><au>Sekiyama, Akira</au><au>Okumura, Mitsutaka</au><au>Konno, Takumi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Valence Interconversion of Octahedral Nickel(II/III/IV) Centers</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2017-10-23</date><risdate>2017</risdate><volume>56</volume><issue>44</issue><spage>13762</spage><epage>13766</epage><pages>13762-13766</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Three oxidation states (+2, +3, +4) of an octahedral nickel center were stabilized in a newly prepared RhNiRh trinuclear complex, [Ni{Rh(apt)3}2]n+ (apt=3‐ aminopropanethiolate), in which the nickel center was bound by six thiolato donors sourced from two redox‐inert fac‐[RhIII(apt)3] octahedral units. The three oxidation states of the octahedral nickel center were fully characterized by single‐crystal X‐ray crystallography, as well as spectroscopic, electrochemical, and magnetic measurements; all three were interconvertible, and the conversion was accompanied by changes in color, magnetism, and Jahn–Teller distortion.
Bridge over troubled water: A series of S‐bridged RhNiRh trinuclear complexes capable of supporting an octahedral nickel center in three different oxidation states (+2, +3, +4) have been isolated. Oxidation state interconversion is accompanied by changes in color, magnetism, and geometric Jahn–Teller distortions, with retention of the trinuclear structure.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>28846211</pmid><doi>10.1002/anie.201708169</doi><tpages>5</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0003-2457-0967</orcidid><orcidid>https://orcid.org/0000-0003-4612-5418</orcidid><orcidid>https://orcid.org/0000-0002-3684-0357</orcidid><orcidid>https://orcid.org/0000-0001-5957-2693</orcidid></addata></record> |
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| subjects | Crystallography Electrochemistry high oxidation states Magnetic measurement Magnetism Nickel Oxidation redox chemistry Single crystals sulfur ligands X-ray crystallography |
| title | Valence Interconversion of Octahedral Nickel(II/III/IV) Centers |
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