Silver-Catalyzed Decarboxylative Trifluoromethylation of Aliphatic Carboxylic Acids

The silver-catalyzed decarboxylative trifluoromethylation of aliphatic carboxylic acids is described. With AgNO3 as the catalyst and K2S2O8 as the oxidant, the reactions of aliphatic carboxylic acids with (bpy)­Cu­(CF3)3 (bpy = 2,2′-bipyridine) and ZnMe2 in aqueous acetonitrile at 40 °C afford the c...

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Veröffentlicht in:	Journal of the American Chemical Society 2017-09, Vol.139 (36), p.12430-12433
Hauptverfasser:	Tan, Xinqiang, Liu, Zhonglin, Shen, Haigen, Zhang, Pei, Zhang, Zhenzhen, Li, Chaozhong
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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