Formation of Olefins by Eliminative Dimerization and Eliminative Cross‐Coupling of Carbenoids: A Stereochemical Exercise

Two carbenoids combine to generate an olefin by a mechanism involving formation of an ate complex, 1,2‐metalate rearrangement, and β‐elimination. As each stage of this eliminative coupling is stereospecific, the overall stereochemical outcome can be understood and, in principle fully controlled, pro...

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Veröffentlicht in:	Angewandte Chemie International Edition 2018-01, Vol.57 (2), p.390-407
Hauptverfasser:	Blakemore, Paul R., Hoffmann, Reinhard W.
Format:	Artikel
Sprache:	eng
Schlagworte:	alkene synthesis Alkenes Carbamates (tradename) carbenoids Cross coupling Dimerization Epoxides Hybridization Isomers Reviews stereoablation stereochemistry stereospecific transformations
Online-Zugang:	Volltext
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