Overview: Nucleation of clathrate hydrates

Molecular level knowledge of nucleation and growth of clathrate hydrates is of importance for advancing fundamental understanding on the nature of water and hydrophobic hydrate formers, and their interactions that result in the formation of ice-like solids at temperatures higher than the ice-point....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 2016-12, Vol.145 (21), p.211705-211705
Hauptverfasser: Warrier, Pramod, Khan, M. Naveed, Srivastava, Vishal, Maupin, C. Mark, Koh, Carolyn A.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 211705
container_issue 21
container_start_page 211705
container_title The Journal of chemical physics
container_volume 145
creator Warrier, Pramod
Khan, M. Naveed
Srivastava, Vishal
Maupin, C. Mark
Koh, Carolyn A.
description Molecular level knowledge of nucleation and growth of clathrate hydrates is of importance for advancing fundamental understanding on the nature of water and hydrophobic hydrate formers, and their interactions that result in the formation of ice-like solids at temperatures higher than the ice-point. The stochastic nature and the inability to probe the small length and time scales associated with the nucleation process make it very difficult to experimentally determine the molecular level changes that lead to the nucleation event. Conversely, for this reason, there have been increasing efforts to obtain this information using molecular simulations. Accurate knowledge of how and when hydrate structures nucleate will be tremendously beneficial for the development of sustainable hydrate management strategies in oil and gas flowlines, as well as for their application in energy storage and recovery, gas separation, carbon sequestration, seawater desalination, and refrigeration. This article reviews various aspects of hydrate nucleation. First, properties of supercooled water and ice nucleation are reviewed briefly due to their apparent similarity to hydrates. Hydrate nucleation is then reviewed starting from macroscopic observations as obtained from experiments in laboratories and operations in industries, followed by various hydrate nucleation hypotheses and hydrate nucleation driving force calculations based on the classical nucleation theory. Finally, molecular simulations on hydrate nucleation are discussed in detail followed by potential future research directions.
doi_str_mv 10.1063/1.4968590
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1928507591</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2121515377</sourcerecordid><originalsourceid>FETCH-LOGICAL-c348t-8812b4bb08e6bcb331382f216ea0a48af006a1cb63fd4243b61dc434539df0533</originalsourceid><addsrcrecordid>eNp90E9LwzAYx_EgipvTg29ABl5U6HyeJE0TbzL8B8Nd9BySNGUd3TqTdrJ3b-emBw-ensuHHw9fQs4RRgiC3eKIKyFTBQekjyBVkgkFh6QPQDFRAkSPnMQ4BwDMKD8mPSozpRinfXIzXfuwLv3n3fC1dZU3TVkvh3UxdJVpZsE0fjjb5NsbT8lRYaroz_Z3QN4fH97Gz8lk-vQyvp8kjnHZJFIitdxakF5YZxlDJmlBUXgDhktTAAiDzgpW5JxyZgXmjjOeMpUXkDI2IFe73VWoP1ofG70oo_NVZZa-bqNGRWUKWaqwo5d_6Lxuw7L7TlOkmGLKsqxT1zvlQh1j8IVehXJhwkYj6G1AjXofsLMX-8XWLnz-K3-KdeBmB6Irm-9a_6x9AbBadSU</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2121515377</pqid></control><display><type>article</type><title>Overview: Nucleation of clathrate hydrates</title><source>AIP Journals Complete</source><source>Alma/SFX Local Collection</source><creator>Warrier, Pramod ; Khan, M. Naveed ; Srivastava, Vishal ; Maupin, C. Mark ; Koh, Carolyn A.</creator><creatorcontrib>Warrier, Pramod ; Khan, M. Naveed ; Srivastava, Vishal ; Maupin, C. Mark ; Koh, Carolyn A.</creatorcontrib><description>Molecular level knowledge of nucleation and growth of clathrate hydrates is of importance for advancing fundamental understanding on the nature of water and hydrophobic hydrate formers, and their interactions that result in the formation of ice-like solids at temperatures higher than the ice-point. The stochastic nature and the inability to probe the small length and time scales associated with the nucleation process make it very difficult to experimentally determine the molecular level changes that lead to the nucleation event. Conversely, for this reason, there have been increasing efforts to obtain this information using molecular simulations. Accurate knowledge of how and when hydrate structures nucleate will be tremendously beneficial for the development of sustainable hydrate management strategies in oil and gas flowlines, as well as for their application in energy storage and recovery, gas separation, carbon sequestration, seawater desalination, and refrigeration. This article reviews various aspects of hydrate nucleation. First, properties of supercooled water and ice nucleation are reviewed briefly due to their apparent similarity to hydrates. Hydrate nucleation is then reviewed starting from macroscopic observations as obtained from experiments in laboratories and operations in industries, followed by various hydrate nucleation hypotheses and hydrate nucleation driving force calculations based on the classical nucleation theory. Finally, molecular simulations on hydrate nucleation are discussed in detail followed by potential future research directions.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.4968590</identifier><identifier>PMID: 28799342</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>United States: American Institute of Physics</publisher><subject>Carbon sequestration ; Desalination ; Energy recovery ; Energy storage ; Gas hydrates ; Gas separation ; Ice formation ; Nucleation ; Physics ; Refrigeration ; Seawater ; Sustainable development</subject><ispartof>The Journal of chemical physics, 2016-12, Vol.145 (21), p.211705-211705</ispartof><rights>Author(s)</rights><rights>2016 Author(s). Published by AIP Publishing.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c348t-8812b4bb08e6bcb331382f216ea0a48af006a1cb63fd4243b61dc434539df0533</citedby><cites>FETCH-LOGICAL-c348t-8812b4bb08e6bcb331382f216ea0a48af006a1cb63fd4243b61dc434539df0533</cites><orcidid>0000-0003-1260-5480 ; 0000-0001-8593-7035 ; 0000-0003-0420-6842 ; 0000000304206842 ; 0000000185937035 ; 0000000312605480</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://pubs.aip.org/jcp/article-lookup/doi/10.1063/1.4968590$$EHTML$$P50$$Gscitation$$H</linktohtml><link.rule.ids>314,777,781,791,4498,27905,27906,76133</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28799342$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Warrier, Pramod</creatorcontrib><creatorcontrib>Khan, M. Naveed</creatorcontrib><creatorcontrib>Srivastava, Vishal</creatorcontrib><creatorcontrib>Maupin, C. Mark</creatorcontrib><creatorcontrib>Koh, Carolyn A.</creatorcontrib><title>Overview: Nucleation of clathrate hydrates</title><title>The Journal of chemical physics</title><addtitle>J Chem Phys</addtitle><description>Molecular level knowledge of nucleation and growth of clathrate hydrates is of importance for advancing fundamental understanding on the nature of water and hydrophobic hydrate formers, and their interactions that result in the formation of ice-like solids at temperatures higher than the ice-point. The stochastic nature and the inability to probe the small length and time scales associated with the nucleation process make it very difficult to experimentally determine the molecular level changes that lead to the nucleation event. Conversely, for this reason, there have been increasing efforts to obtain this information using molecular simulations. Accurate knowledge of how and when hydrate structures nucleate will be tremendously beneficial for the development of sustainable hydrate management strategies in oil and gas flowlines, as well as for their application in energy storage and recovery, gas separation, carbon sequestration, seawater desalination, and refrigeration. This article reviews various aspects of hydrate nucleation. First, properties of supercooled water and ice nucleation are reviewed briefly due to their apparent similarity to hydrates. Hydrate nucleation is then reviewed starting from macroscopic observations as obtained from experiments in laboratories and operations in industries, followed by various hydrate nucleation hypotheses and hydrate nucleation driving force calculations based on the classical nucleation theory. Finally, molecular simulations on hydrate nucleation are discussed in detail followed by potential future research directions.</description><subject>Carbon sequestration</subject><subject>Desalination</subject><subject>Energy recovery</subject><subject>Energy storage</subject><subject>Gas hydrates</subject><subject>Gas separation</subject><subject>Ice formation</subject><subject>Nucleation</subject><subject>Physics</subject><subject>Refrigeration</subject><subject>Seawater</subject><subject>Sustainable development</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp90E9LwzAYx_EgipvTg29ABl5U6HyeJE0TbzL8B8Nd9BySNGUd3TqTdrJ3b-emBw-ensuHHw9fQs4RRgiC3eKIKyFTBQekjyBVkgkFh6QPQDFRAkSPnMQ4BwDMKD8mPSozpRinfXIzXfuwLv3n3fC1dZU3TVkvh3UxdJVpZsE0fjjb5NsbT8lRYaroz_Z3QN4fH97Gz8lk-vQyvp8kjnHZJFIitdxakF5YZxlDJmlBUXgDhktTAAiDzgpW5JxyZgXmjjOeMpUXkDI2IFe73VWoP1ofG70oo_NVZZa-bqNGRWUKWaqwo5d_6Lxuw7L7TlOkmGLKsqxT1zvlQh1j8IVehXJhwkYj6G1AjXofsLMX-8XWLnz-K3-KdeBmB6Irm-9a_6x9AbBadSU</recordid><startdate>20161207</startdate><enddate>20161207</enddate><creator>Warrier, Pramod</creator><creator>Khan, M. Naveed</creator><creator>Srivastava, Vishal</creator><creator>Maupin, C. Mark</creator><creator>Koh, Carolyn A.</creator><general>American Institute of Physics</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1260-5480</orcidid><orcidid>https://orcid.org/0000-0001-8593-7035</orcidid><orcidid>https://orcid.org/0000-0003-0420-6842</orcidid><orcidid>https://orcid.org/0000000304206842</orcidid><orcidid>https://orcid.org/0000000185937035</orcidid><orcidid>https://orcid.org/0000000312605480</orcidid></search><sort><creationdate>20161207</creationdate><title>Overview: Nucleation of clathrate hydrates</title><author>Warrier, Pramod ; Khan, M. Naveed ; Srivastava, Vishal ; Maupin, C. Mark ; Koh, Carolyn A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c348t-8812b4bb08e6bcb331382f216ea0a48af006a1cb63fd4243b61dc434539df0533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Carbon sequestration</topic><topic>Desalination</topic><topic>Energy recovery</topic><topic>Energy storage</topic><topic>Gas hydrates</topic><topic>Gas separation</topic><topic>Ice formation</topic><topic>Nucleation</topic><topic>Physics</topic><topic>Refrigeration</topic><topic>Seawater</topic><topic>Sustainable development</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Warrier, Pramod</creatorcontrib><creatorcontrib>Khan, M. Naveed</creatorcontrib><creatorcontrib>Srivastava, Vishal</creatorcontrib><creatorcontrib>Maupin, C. Mark</creatorcontrib><creatorcontrib>Koh, Carolyn A.</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Warrier, Pramod</au><au>Khan, M. Naveed</au><au>Srivastava, Vishal</au><au>Maupin, C. Mark</au><au>Koh, Carolyn A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Overview: Nucleation of clathrate hydrates</atitle><jtitle>The Journal of chemical physics</jtitle><addtitle>J Chem Phys</addtitle><date>2016-12-07</date><risdate>2016</risdate><volume>145</volume><issue>21</issue><spage>211705</spage><epage>211705</epage><pages>211705-211705</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>Molecular level knowledge of nucleation and growth of clathrate hydrates is of importance for advancing fundamental understanding on the nature of water and hydrophobic hydrate formers, and their interactions that result in the formation of ice-like solids at temperatures higher than the ice-point. The stochastic nature and the inability to probe the small length and time scales associated with the nucleation process make it very difficult to experimentally determine the molecular level changes that lead to the nucleation event. Conversely, for this reason, there have been increasing efforts to obtain this information using molecular simulations. Accurate knowledge of how and when hydrate structures nucleate will be tremendously beneficial for the development of sustainable hydrate management strategies in oil and gas flowlines, as well as for their application in energy storage and recovery, gas separation, carbon sequestration, seawater desalination, and refrigeration. This article reviews various aspects of hydrate nucleation. First, properties of supercooled water and ice nucleation are reviewed briefly due to their apparent similarity to hydrates. Hydrate nucleation is then reviewed starting from macroscopic observations as obtained from experiments in laboratories and operations in industries, followed by various hydrate nucleation hypotheses and hydrate nucleation driving force calculations based on the classical nucleation theory. Finally, molecular simulations on hydrate nucleation are discussed in detail followed by potential future research directions.</abstract><cop>United States</cop><pub>American Institute of Physics</pub><pmid>28799342</pmid><doi>10.1063/1.4968590</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-1260-5480</orcidid><orcidid>https://orcid.org/0000-0001-8593-7035</orcidid><orcidid>https://orcid.org/0000-0003-0420-6842</orcidid><orcidid>https://orcid.org/0000000304206842</orcidid><orcidid>https://orcid.org/0000000185937035</orcidid><orcidid>https://orcid.org/0000000312605480</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0021-9606
ispartof The Journal of chemical physics, 2016-12, Vol.145 (21), p.211705-211705
issn 0021-9606
1089-7690
language eng
recordid cdi_proquest_miscellaneous_1928507591
source AIP Journals Complete; Alma/SFX Local Collection
subjects Carbon sequestration
Desalination
Energy recovery
Energy storage
Gas hydrates
Gas separation
Ice formation
Nucleation
Physics
Refrigeration
Seawater
Sustainable development
title Overview: Nucleation of clathrate hydrates
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T10%3A05%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Overview:%20Nucleation%20of%20clathrate%20hydrates&rft.jtitle=The%20Journal%20of%20chemical%20physics&rft.au=Warrier,%20Pramod&rft.date=2016-12-07&rft.volume=145&rft.issue=21&rft.spage=211705&rft.epage=211705&rft.pages=211705-211705&rft.issn=0021-9606&rft.eissn=1089-7690&rft.coden=JCPSA6&rft_id=info:doi/10.1063/1.4968590&rft_dat=%3Cproquest_cross%3E2121515377%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2121515377&rft_id=info:pmid/28799342&rfr_iscdi=true