Mechanochemical synthesis of two-dimensional aromatic polyamides
Herein we report a facile mechanochemical synthesis of 2D aromatic polyamides (2DAPAs) under solvent-free and room temperature conditions for the first time. The solvent-free conditions are found to be key to the successful synthesis of 2DAPAs. These micrometer-size 2DAPAs have ultrathin graphene-li...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2017, Vol.53 (54), p.7481-7484 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Yang, Yang Bu, Fanxing Liu, Jingjing Shakir, Imran Xu, Yuxi |
description | Herein we report a facile mechanochemical synthesis of 2D aromatic polyamides (2DAPAs) under solvent-free and room temperature conditions for the first time. The solvent-free conditions are found to be key to the successful synthesis of 2DAPAs. These micrometer-size 2DAPAs have ultrathin graphene-like structures and are highly crystalline, solvent dispersible and thermally stable up to 400 °C. |
doi_str_mv | 10.1039/c7cc02648j |
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subjects | Aromatic polyamides Crystal structure Dispersion Mechanochemistry Solvents Synthesis Thermal stability |
title | Mechanochemical synthesis of two-dimensional aromatic polyamides |
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