Mononuclear Rhodium(II) and Iridium(II) Complexes Supported by Tetradentate Pyridinophane Ligands

The tetradentate ligands N,N′-dialkyl-2,11-diaza­[3,3]­(2,6)­pyridinophane (RN4, where R = Me or tBu) were employed to synthesize and fully characterize [(RN4)­MI(COD)]+ complexes (M = Rh or Ir; COD = cyclooctadiene). Interestingly, these complexes exhibit accessible oxidation potentials and can gen...

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Veröffentlicht in:	Inorganic chemistry 2017-08, Vol.56 (16), p.9404-9408
Hauptverfasser:	Fuchigami, Kei, Rath, Nigam P, Mirica, Liviu M
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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