Enhanced treatment of secondary municipal wastewater effluent: comparing (biological) filtration and ozonation in view of micropollutant removal, unselective effluent toxicity, and the potential for real-time control

Ozonation and three (biological) filtration techniques (trickling filtration (TF), slow sand filtration (SSF) and biological activated carbon (BAC) filtration) have been evaluated in different combinations as tertiary treatment for municipal wastewater effluent. The removal of 18 multi-class pharmac...

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Veröffentlicht in:Water science and technology 2017-07, Vol.76 (1-2), p.236-246
Hauptverfasser: Chys, Michael, Demeestere, Kristof, Ingabire, Ange Sabine, Dries, Jan, Van Langenhove, Herman, Van Hulle, Stijn W H
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container_issue 1-2
container_start_page 236
container_title Water science and technology
container_volume 76
creator Chys, Michael
Demeestere, Kristof
Ingabire, Ange Sabine
Dries, Jan
Van Langenhove, Herman
Van Hulle, Stijn W H
description Ozonation and three (biological) filtration techniques (trickling filtration (TF), slow sand filtration (SSF) and biological activated carbon (BAC) filtration) have been evaluated in different combinations as tertiary treatment for municipal wastewater effluent. The removal of 18 multi-class pharmaceuticals, as model trace organic contaminants (TrOCs), has been studied. (Biological) activated carbon filtration could reduce the amount of TrOCs significantly (>99%) but is cost-intensive for full-scale applications. Filtration techniques mainly depending on biodegradation mechanisms (TF and SSF) are found to be inefficient for TrOCs removal as a stand alone technique. Ozonation resulted in 90% removal of the total amount of quantified TrOCs, but a post-ozonation step is needed to cope with an increased unselective toxicity. SSF following ozonation showed to be the only technique able to reduce the unselective toxicity to the same level as before ozonation. In view of process control, innovative correlation models developed for the monitoring and control of TrOC removal during ozonation, are verified for their applicability during ozonation in combination with TF, SSF or BAC. Particularly for the poorly ozone reactive TrOCs, statistically significant models were obtained that correlate TrOC removal and reduction in UVA as an online measured surrogate parameter.
doi_str_mv 10.2166/wst.2017.207
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subjects Activated carbon
Adsorption
Biodegradation
Biofiltration
Charcoal - chemistry
Contaminants
Control
Cost engineering
Drinking water
Effluents
Filtration
Filtration - instrumentation
Filtration - methods
Micropollutants
Municipal wastewater
Organic contaminants
Oxidation
Ozonation
Ozone
Ozone - chemistry
Ozonization
Personal grooming
Pharmaceuticals
Pollutant removal
Process control
Real time
Removal
Secondary wastewater
Silicon Dioxide - chemistry
Statistical analysis
Toxicity
Waste Disposal, Fluid - instrumentation
Waste Disposal, Fluid - methods
Waste Water - chemistry
Wastewater
Wastewater treatment
Water Pollutants, Chemical - chemistry
title Enhanced treatment of secondary municipal wastewater effluent: comparing (biological) filtration and ozonation in view of micropollutant removal, unselective effluent toxicity, and the potential for real-time control
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