Formation of plate boundaries: The role of mantle volatilization

In the early Earth, convection occurred with the accumulation of thick crust over a weak boundary layer downwelling into the mantle (Davies, G.F., 1992. On the emergence of plate tectonics. Geology 20, 963–966.). This would have transitioned to stagnant-lid convection as the mantle cooled (Solomatov, V.S., Moresi, L.-N., 1997. Three regimes of mantle convection with non-Newtonian viscosity and stagnant lid convection on the terrestrial planets. Geophys. Res. Lett. 24, 1907–1910.) or back to a magma ocean as the mantle heated (Sleep, N., 2000. Evolution of the mode of convection within terrestrial planets. J. Geophys. Res. 105(E7): 17563–17578). Because plate tectonics began operating on the Earth, subduction must have been initiated, thus avoiding these shifts. Based on an analogy with the continental crust subducted beneath Hindu Kush and Burma, we propose that the lithosphere was hydrated and/or carbonated by H2O–CO2 vapors released from magmas generated in upwelling plumes and subsequently volatilized during underthrusting, resulting in lubrication of the thrust above, and subduction of the lithosphere along with the overlying thick crust. Once subduction had been initiated, serpentinized forearc mantle may have formed in a wedge-shaped body above a dehydrating slab. In relict arcs, suture zones, or rifted margins, any agent that warms and dehydrates the wedge would weaken the region surrounding it, and form various types of plate boundaries depending on the operating tectonic stress. Thus, once subduction is initiated, formation of plate boundaries might be facilitated by a major fundamental process: weakening due to the release of pressurized water from the warming serpentinized forearc mantle.