Detecting Molecular Rotational Dynamics Complementing the Low-Frequency Terahertz Vibrations in a Zirconium-Based Metal-Organic Framework

We show clear experimental evidence of cooperative terahertz (THz) dynamics observed below 3 THz (∼100  cm^{-1}), for a low-symmetry Zr-based metal-organic framework structure, termed MIL-140A [ZrO(O_{2}C-C_{6}H_{4}-CO_{2})]. Utilizing a combination of high-resolution inelastic neutron scattering an...

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Veröffentlicht in:	Physical review letters 2017-06, Vol.118 (25), p.255502-255502, Article 255502
Hauptverfasser:	Ryder, Matthew R, Van de Voorde, Ben, Civalleri, Bartolomeo, Bennett, Thomas D, Mukhopadhyay, Sanghamitra, Cinque, Gianfelice, Fernandez-Alonso, Felix, De Vos, Dirk, Rudić, Svemir, Tan, Jin-Chong
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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