Highly Fluorescent Pyridinium Betaines for Light Harvesting
We report the findings of our experimental and theoretical investigations into the properties of pyridinium enolates and their potential utility in light‐harvesting applications, such as in luminescent solar concentrators (LSCs). We present the synthesis, structures, photophysical characterization,...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2017-10, Vol.56 (44), p.13882-13886 |
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| container_issue | 44 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Xu, Jingjing Zhang, Bolong Jansen, Marina Goerigk, Lars Wong, Wallace W. H. Ritchie, Chris |
| description | We report the findings of our experimental and theoretical investigations into the properties of pyridinium enolates and their potential utility in light‐harvesting applications, such as in luminescent solar concentrators (LSCs). We present the synthesis, structures, photophysical characterization, and wavefunction‐based quantum‐chemical studies of five cyclobetaines. The performance of an LSC device incorporating one of these cyclobetaines is shown to be comparable to state‐of‐the‐art devices.
Experiment and theory: Pyridinium enolates and their potential utility in light‐harvesting applications, such as in luminescent solar concentrators, were studied experimentally and theoretically. The synthesis, structures, photophysical properties, and wavefunction‐based quantum‐chemical studies of five cyclobetaines are presented. |
| doi_str_mv | 10.1002/anie.201704832 |
| format | Article |
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Experiment and theory: Pyridinium enolates and their potential utility in light‐harvesting applications, such as in luminescent solar concentrators, were studied experimentally and theoretically. The synthesis, structures, photophysical properties, and wavefunction‐based quantum‐chemical studies of five cyclobetaines are presented.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201704832</identifier><identifier>PMID: 28695638</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Betaines ; Chemical synthesis ; Concentrators ; energy transfer ; Fluorescence ; fluorophores ; luminescent solar concentrators ; Pyridinium ; Quantum chemistry</subject><ispartof>Angewandte Chemie International Edition, 2017-10, Vol.56 (44), p.13882-13886</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5162-2a3d08b71bcc18ba0eebbb6bde4f8896c3d1b5ed720ca7d7647b9ebb9ba108413</citedby><cites>FETCH-LOGICAL-c5162-2a3d08b71bcc18ba0eebbb6bde4f8896c3d1b5ed720ca7d7647b9ebb9ba108413</cites><orcidid>0000-0002-3838-624X ; 0000-0002-0293-6959 ; 0000-0003-3155-675X ; 0000-0002-2955-8409 ; 0000-0002-1640-6406 ; 0000-0001-7131-8532</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201704832$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201704832$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28695638$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Xu, Jingjing</creatorcontrib><creatorcontrib>Zhang, Bolong</creatorcontrib><creatorcontrib>Jansen, Marina</creatorcontrib><creatorcontrib>Goerigk, Lars</creatorcontrib><creatorcontrib>Wong, Wallace W. H.</creatorcontrib><creatorcontrib>Ritchie, Chris</creatorcontrib><title>Highly Fluorescent Pyridinium Betaines for Light Harvesting</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>We report the findings of our experimental and theoretical investigations into the properties of pyridinium enolates and their potential utility in light‐harvesting applications, such as in luminescent solar concentrators (LSCs). We present the synthesis, structures, photophysical characterization, and wavefunction‐based quantum‐chemical studies of five cyclobetaines. The performance of an LSC device incorporating one of these cyclobetaines is shown to be comparable to state‐of‐the‐art devices.
Experiment and theory: Pyridinium enolates and their potential utility in light‐harvesting applications, such as in luminescent solar concentrators, were studied experimentally and theoretically. The synthesis, structures, photophysical properties, and wavefunction‐based quantum‐chemical studies of five cyclobetaines are presented.</description><subject>Betaines</subject><subject>Chemical synthesis</subject><subject>Concentrators</subject><subject>energy transfer</subject><subject>Fluorescence</subject><subject>fluorophores</subject><subject>luminescent solar concentrators</subject><subject>Pyridinium</subject><subject>Quantum chemistry</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqF0DtPwzAUBWALgWgprIwoEgtLih-JH2KCqqWVKmCA2bITp7jKo9gJKP8eVy1FYmG6Hj6fe3UAuERwjCDEt6q2ZowhYjDhBB-BIUoxiglj5Di8E0JixlM0AGfer4PnHNJTMMCcipQSPgR3c7t6L_toVnaNMz4zdRu99M7mtrZdFT2YVtna-KhoXLQMtI3myn0a39p6dQ5OClV6c7GfI_A2m75O5vHy-XExuV_GWYoojrEiOeSaIZ1liGsFjdFaU52bpOBc0IzkSKcmZxhmiuWMJkyLQIRWCPIEkRG42eVuXPPRhd2ysuHSslS1aTovkUBMpEJAGuj1H7puOleH64JKEaeJYCSo8U5lrvHemUJunK2U6yWCclur3NYqD7WGD1f72E5XJj_wnx4DEDvwZUvT_xMn758W09_wb-Kmg9k</recordid><startdate>20171023</startdate><enddate>20171023</enddate><creator>Xu, Jingjing</creator><creator>Zhang, Bolong</creator><creator>Jansen, Marina</creator><creator>Goerigk, Lars</creator><creator>Wong, Wallace W. H.</creator><creator>Ritchie, Chris</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-3838-624X</orcidid><orcidid>https://orcid.org/0000-0002-0293-6959</orcidid><orcidid>https://orcid.org/0000-0003-3155-675X</orcidid><orcidid>https://orcid.org/0000-0002-2955-8409</orcidid><orcidid>https://orcid.org/0000-0002-1640-6406</orcidid><orcidid>https://orcid.org/0000-0001-7131-8532</orcidid></search><sort><creationdate>20171023</creationdate><title>Highly Fluorescent Pyridinium Betaines for Light Harvesting</title><author>Xu, Jingjing ; Zhang, Bolong ; Jansen, Marina ; Goerigk, Lars ; Wong, Wallace W. H. ; Ritchie, Chris</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5162-2a3d08b71bcc18ba0eebbb6bde4f8896c3d1b5ed720ca7d7647b9ebb9ba108413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Betaines</topic><topic>Chemical synthesis</topic><topic>Concentrators</topic><topic>energy transfer</topic><topic>Fluorescence</topic><topic>fluorophores</topic><topic>luminescent solar concentrators</topic><topic>Pyridinium</topic><topic>Quantum chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Jingjing</creatorcontrib><creatorcontrib>Zhang, Bolong</creatorcontrib><creatorcontrib>Jansen, Marina</creatorcontrib><creatorcontrib>Goerigk, Lars</creatorcontrib><creatorcontrib>Wong, Wallace W. H.</creatorcontrib><creatorcontrib>Ritchie, Chris</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Jingjing</au><au>Zhang, Bolong</au><au>Jansen, Marina</au><au>Goerigk, Lars</au><au>Wong, Wallace W. H.</au><au>Ritchie, Chris</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Fluorescent Pyridinium Betaines for Light Harvesting</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2017-10-23</date><risdate>2017</risdate><volume>56</volume><issue>44</issue><spage>13882</spage><epage>13886</epage><pages>13882-13886</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>We report the findings of our experimental and theoretical investigations into the properties of pyridinium enolates and their potential utility in light‐harvesting applications, such as in luminescent solar concentrators (LSCs). We present the synthesis, structures, photophysical characterization, and wavefunction‐based quantum‐chemical studies of five cyclobetaines. The performance of an LSC device incorporating one of these cyclobetaines is shown to be comparable to state‐of‐the‐art devices.
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| subjects | Betaines Chemical synthesis Concentrators energy transfer Fluorescence fluorophores luminescent solar concentrators Pyridinium Quantum chemistry |
| title | Highly Fluorescent Pyridinium Betaines for Light Harvesting |
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