Observation of nanoimpact events of catalase on diamond ultramicroelectrodes by direct electron transfer

We report electrochemical detection of single-catalase collisions at diamond ultramicroelectrodes and show the operative mechanism involves direct enzyme-mediated charge transfer between electrode and solution. Hydrogen peroxide increases the collision frequency, which fluorescence correlation spect...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2017-07, Vol.53 (59), p.8332-8335
Hauptverfasser: Jiang, Luyun, Santiago, Ibon, Foord, John
Format: Artikel
Sprache:eng
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