Intricate kinetics: in situ FTIR-spectroscopy discloses a phase change during ionic liquid synthesis

The kinetics of the methylation of triethylamine (NEt ) with dimethyl carbonate (DMC) in methanol have been investigated by means of in situ ATR-IR-spectroscopy. The data show an autocatalytic influence of the ionic product on reaction kinetics. A bend in the reaction rate progress indicates a sudde...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2017-07, Vol.19 (27), p.18018-18022
Hauptverfasser:	Ohligschläger, A, Liauw, M A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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