One-pot enyne metathesis/Diels-Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores

Polycyclic compounds containing a six-membered silacycle are important. However, we have limited knowledge of the nature of these six-membered silacycles because methodologies for their synthesis remain under-developed. Here, we have developed a one-pot enyne metathesis/Diels-Alder/oxidation methodo...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2017-05, Vol.53 (44), p.5970-5973
Hauptverfasser:	Yoshioka, Shohei, Fujii, Yuki, Tsujino, Hirofumi, Uno, Tadayuki, Fujioka, Hiromichi, Arisawa, Mitsuhiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical compounds Decomposition reactions Fluorescence Metathesis Oxidation Synthesis
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	5973
container_issue	44
container_start_page	5970
container_title	Chemical communications (Cambridge, England)
container_volume	53
creator	Yoshioka, Shohei Fujii, Yuki Tsujino, Hirofumi Uno, Tadayuki Fujioka, Hiromichi Arisawa, Mitsuhiro
description	Polycyclic compounds containing a six-membered silacycle are important. However, we have limited knowledge of the nature of these six-membered silacycles because methodologies for their synthesis remain under-developed. Here, we have developed a one-pot enyne metathesis/Diels-Alder/oxidation methodology for the synthesis of six-membered silacycles. Some of these compounds are novel fluorophores.
doi_str_mv	10.1039/c7cc02788e
format	Article
fullrecord	<record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1915325160</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1896412534</sourcerecordid><originalsourceid>FETCH-LOGICAL-c320t-64df49b26f0b1be9a17843407093642d16ec539a54ee8ffece8c8bf1b20570a03</originalsourceid><addsrcrecordid>eNqNkUtr3TAQhUVoyXvTHxC0LAX1SpZkS9kFN49CIJsGsjOyPMpVka0bSW5yl_3ncV5ddzZzhvk4zHAQ-sLod0a5XtnGWlo1SsEO2me8FkQKdffpRUtNGi7kHjrI-Tddikm1i_YqJRQVUu-jvzcTkE0sGKbtBHiEYsoass-rHx5CJmdhgLSKT34wxccJl4izfyIjjD0kGJYhGLu1ATJ-9GWNDR7nUDxJfrrHNiY4xYPPNv6BtMXR4WlRAbswxxQ362Wfj9BnZ0KG4_d-iG4vzn-1V-T65vJne3ZNLK9oIbUYnNB9VTvasx60YY0SXNCG6uXjamA1WMm1kQJAOQcWlFW9Y31FZUMN5Yfo65vvJsWHGXLpxuUwCMFMEOfcMc0krySr_wNVuhasklws6Lc31KaYcwLXbZIfTdp2jHYv6XRt07av6Zwv8Mm779yPMPxDP-Lgz5JUjD0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1896412534</pqid></control><display><type>article</type><title>One-pot enyne metathesis/Diels-Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Yoshioka, Shohei ; Fujii, Yuki ; Tsujino, Hirofumi ; Uno, Tadayuki ; Fujioka, Hiromichi ; Arisawa, Mitsuhiro</creator><creatorcontrib>Yoshioka, Shohei ; Fujii, Yuki ; Tsujino, Hirofumi ; Uno, Tadayuki ; Fujioka, Hiromichi ; Arisawa, Mitsuhiro</creatorcontrib><description>Polycyclic compounds containing a six-membered silacycle are important. However, we have limited knowledge of the nature of these six-membered silacycles because methodologies for their synthesis remain under-developed. Here, we have developed a one-pot enyne metathesis/Diels-Alder/oxidation methodology for the synthesis of six-membered silacycles. Some of these compounds are novel fluorophores.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c7cc02788e</identifier><identifier>PMID: 28480459</identifier><language>eng</language><publisher>England</publisher><subject>Chemical compounds ; Decomposition reactions ; Fluorescence ; Metathesis ; Oxidation ; Synthesis</subject><ispartof>Chemical communications (Cambridge, England), 2017-05, Vol.53 (44), p.5970-5973</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c320t-64df49b26f0b1be9a17843407093642d16ec539a54ee8ffece8c8bf1b20570a03</citedby><cites>FETCH-LOGICAL-c320t-64df49b26f0b1be9a17843407093642d16ec539a54ee8ffece8c8bf1b20570a03</cites><orcidid>0000-0001-5575-2988 ; 0000-0003-0926-5876 ; 0000-0002-9970-4248 ; 0000-0003-2056-5781 ; 0000-0002-7937-670X ; 0000-0002-0057-2039</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28480459$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Yoshioka, Shohei</creatorcontrib><creatorcontrib>Fujii, Yuki</creatorcontrib><creatorcontrib>Tsujino, Hirofumi</creatorcontrib><creatorcontrib>Uno, Tadayuki</creatorcontrib><creatorcontrib>Fujioka, Hiromichi</creatorcontrib><creatorcontrib>Arisawa, Mitsuhiro</creatorcontrib><title>One-pot enyne metathesis/Diels-Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>Polycyclic compounds containing a six-membered silacycle are important. However, we have limited knowledge of the nature of these six-membered silacycles because methodologies for their synthesis remain under-developed. Here, we have developed a one-pot enyne metathesis/Diels-Alder/oxidation methodology for the synthesis of six-membered silacycles. Some of these compounds are novel fluorophores.</description><subject>Chemical compounds</subject><subject>Decomposition reactions</subject><subject>Fluorescence</subject><subject>Metathesis</subject><subject>Oxidation</subject><subject>Synthesis</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNkUtr3TAQhUVoyXvTHxC0LAX1SpZkS9kFN49CIJsGsjOyPMpVka0bSW5yl_3ncV5ddzZzhvk4zHAQ-sLod0a5XtnGWlo1SsEO2me8FkQKdffpRUtNGi7kHjrI-Tddikm1i_YqJRQVUu-jvzcTkE0sGKbtBHiEYsoass-rHx5CJmdhgLSKT34wxccJl4izfyIjjD0kGJYhGLu1ATJ-9GWNDR7nUDxJfrrHNiY4xYPPNv6BtMXR4WlRAbswxxQ362Wfj9BnZ0KG4_d-iG4vzn-1V-T65vJne3ZNLK9oIbUYnNB9VTvasx60YY0SXNCG6uXjamA1WMm1kQJAOQcWlFW9Y31FZUMN5Yfo65vvJsWHGXLpxuUwCMFMEOfcMc0krySr_wNVuhasklws6Lc31KaYcwLXbZIfTdp2jHYv6XRt07av6Zwv8Mm779yPMPxDP-Lgz5JUjD0</recordid><startdate>20170530</startdate><enddate>20170530</enddate><creator>Yoshioka, Shohei</creator><creator>Fujii, Yuki</creator><creator>Tsujino, Hirofumi</creator><creator>Uno, Tadayuki</creator><creator>Fujioka, Hiromichi</creator><creator>Arisawa, Mitsuhiro</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-5575-2988</orcidid><orcidid>https://orcid.org/0000-0003-0926-5876</orcidid><orcidid>https://orcid.org/0000-0002-9970-4248</orcidid><orcidid>https://orcid.org/0000-0003-2056-5781</orcidid><orcidid>https://orcid.org/0000-0002-7937-670X</orcidid><orcidid>https://orcid.org/0000-0002-0057-2039</orcidid></search><sort><creationdate>20170530</creationdate><title>One-pot enyne metathesis/Diels-Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores</title><author>Yoshioka, Shohei ; Fujii, Yuki ; Tsujino, Hirofumi ; Uno, Tadayuki ; Fujioka, Hiromichi ; Arisawa, Mitsuhiro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-64df49b26f0b1be9a17843407093642d16ec539a54ee8ffece8c8bf1b20570a03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemical compounds</topic><topic>Decomposition reactions</topic><topic>Fluorescence</topic><topic>Metathesis</topic><topic>Oxidation</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yoshioka, Shohei</creatorcontrib><creatorcontrib>Fujii, Yuki</creatorcontrib><creatorcontrib>Tsujino, Hirofumi</creatorcontrib><creatorcontrib>Uno, Tadayuki</creatorcontrib><creatorcontrib>Fujioka, Hiromichi</creatorcontrib><creatorcontrib>Arisawa, Mitsuhiro</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yoshioka, Shohei</au><au>Fujii, Yuki</au><au>Tsujino, Hirofumi</au><au>Uno, Tadayuki</au><au>Fujioka, Hiromichi</au><au>Arisawa, Mitsuhiro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-pot enyne metathesis/Diels-Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2017-05-30</date><risdate>2017</risdate><volume>53</volume><issue>44</issue><spage>5970</spage><epage>5973</epage><pages>5970-5973</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Polycyclic compounds containing a six-membered silacycle are important. However, we have limited knowledge of the nature of these six-membered silacycles because methodologies for their synthesis remain under-developed. Here, we have developed a one-pot enyne metathesis/Diels-Alder/oxidation methodology for the synthesis of six-membered silacycles. Some of these compounds are novel fluorophores.</abstract><cop>England</cop><pmid>28480459</pmid><doi>10.1039/c7cc02788e</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-5575-2988</orcidid><orcidid>https://orcid.org/0000-0003-0926-5876</orcidid><orcidid>https://orcid.org/0000-0002-9970-4248</orcidid><orcidid>https://orcid.org/0000-0003-2056-5781</orcidid><orcidid>https://orcid.org/0000-0002-7937-670X</orcidid><orcidid>https://orcid.org/0000-0002-0057-2039</orcidid></addata></record>
fulltext	fulltext
identifier	ISSN: 1359-7345
ispartof	Chemical communications (Cambridge, England), 2017-05, Vol.53 (44), p.5970-5973
issn	1359-7345 1364-548X
language	eng
recordid	cdi_proquest_miscellaneous_1915325160
source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Chemical compounds Decomposition reactions Fluorescence Metathesis Oxidation Synthesis
title	One-pot enyne metathesis/Diels-Alder/oxidation to six-membered silacycles with a multi-ring core: discovery of novel fluorophores
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-11T10%3A22%3A13IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=One-pot%20enyne%20metathesis/Diels-Alder/oxidation%20to%20six-membered%20silacycles%20with%20a%20multi-ring%20core:%20discovery%20of%20novel%20fluorophores&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Yoshioka,%20Shohei&rft.date=2017-05-30&rft.volume=53&rft.issue=44&rft.spage=5970&rft.epage=5973&rft.pages=5970-5973&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/c7cc02788e&rft_dat=%3Cproquest_cross%3E1896412534%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1896412534&rft_id=info:pmid/28480459&rfr_iscdi=true