TMSCF3 as a Convenient Source of CF2=CF2 for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation

A new method for the on‐site preparation of tetrafluoroethylene (TFE) and a procedure for its efficient use in pentafluoroethylation by fluoride addition were developed by using a simple two‐chamber system. The on‐site preparation of TFE was accomplished by dimerization of difluorocarbene derived fr...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-08, Vol.56 (33), p.9971-9975
Hauptverfasser:	Li, Lingchun, Ni, Chuanfa, Xie, Qiqiang, Hu, Mingyou, Wang, Fei, Hu, Jinbo
Format:	Artikel
Sprache:	eng
Schlagworte:	copper difluorocarbene Dimerization Fluorides pentafluoroethylation tetrafluoroethylation Tetrafluoroethylene
Online-Zugang:	Volltext
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