Transformation of Methylene Acetals to Bromoformates with a Combination of Trimethyl(phenylthio)silane and N‑Bromosuccinimide

A novel transformation reaction of methylene acetals, using a combination of trimethyl­(phenylthio)­silane (PhSTMS) and N-bromosuccinimide (NBS) under mild reaction conditions, is described. Various methylene acetals were converted to their corresponding bromoformates in good to high yields. Under t...

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Veröffentlicht in:	Journal of organic chemistry 2017-07, Vol.82 (14), p.7608-7613
Hauptverfasser:	Maegawa, Tomohiro, Nogata, Misa, Hirose, Yuuka, Ohgami, Shun, Nakamura, Akira, Miki, Yasuyoshi, Fujioka, Hiromichi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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