Magnetostructural Characterization of Oxalamide Dihalo‐Bridged Copper Dimers: Intra‐ and Interdimer Interactions Studied by Single‐Crystal Electron Spin Resonance Spectroscopy

Detailed single‐crystal electron spin resonance (ESR) analysis of oxalamide complexes with halogen‐bridged copper dimers, supported by X‐ray, magnetic susceptibility, and powder ESR studies, is reported. Four complexes with two different ligands are synthesized: [CuLA(μ‐X)]2 and [CuLV(μ‐X)]2, for wh...

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Veröffentlicht in:	Chemphyschem 2017-09, Vol.18 (17), p.2397-2408
Hauptverfasser:	Žilić, Dijana, Maity, Debdeep, Cetina, Mario, Molčanov, Krešimir, Džolić, Zoran, Herak, Mirta
Format:	Artikel
Sprache:	eng
Schlagworte:	Alanine Antiferromagnetism Coordination compounds copper Copper compounds Crystals Dimers dipolar splitting Electron paramagnetic resonance Electron spin Electrons EPR spectroscopy Ground state Hydrogen bonds Magnetic fields Magnetic permeability magnetic properties Magnetic resonance Planes Pyramids Single crystals Spectrum analysis Spin resonance Splitting Valine X ray analysis
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