Total synthesis of marine natural products separacenes A and B

A short and convergent route for the stereoselective total synthesis of separacenes A and B has been developed using (+)-methyl d-lactate and d-(-)-tartaric acid as the chiral pools. The characteristic features of this synthesis include the Trost-Rychnovsky alkyne rearrangement to construct the C -C...

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Veröffentlicht in:	Organic & biomolecular chemistry 2017, Vol.15 (22), p.4842-4850
Hauptverfasser:	Das, Subhendu, Goswami, Rajib Kumar
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological Products - chemical synthesis Biological Products - chemistry Molecular Structure Polyenes - chemical synthesis Polyenes - chemistry Stereoisomerism
Online-Zugang:	Volltext
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