Reaction of Dihalodiboranes(4) with a N‐Heterocyclic Silylene: Facile Construction of 1‐Aryl‐2‐Silyl‐1,2‐Diboraindanes

Dihalodiboranes(4) react with a N‐heterocyclic silylene (NHSi) to generate NHSi adducts of 1‐aryl‐2‐silyl‐1,2‐diboraindanes, as was confirmed by X‐ray crystallography, featuring the functionalization of both B−X (X=halogen) bonds and a sp3‐ or sp2‐C−H bond under mild conditions. Coordination of a th...

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Veröffentlicht in:	Chemistry : a European journal 2017-07, Vol.23 (40), p.9491-9494
Hauptverfasser:	Braunschweig, Holger, Brückner, Tobias, Deißenberger, Andrea, Dewhurst, Rian D., Gackstatter, Annika, Gärtner, Annalena, Hofmann, Alexander, Kupfer, Thomas, Prieschl, Dominic, Thiess, Torsten, Wang, Sunewang Rixin
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Aromatic compounds bond activation borylation Chemistry Crystallography diboraindanes diboranes Hydrogen bonds Insertion Intermediates synthetic methods
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