Synthesis of Photocrosslinkable and Amine Containing Multifunctional Nanoparticles via Polymerization‐Induced Self‐Assembly
Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization‐induced self‐assembly of a multifunctional core‐forming monomer, 2‐((3‐(4‐(diethylamino)phenyl)acryloyl)oxy)ethyl methacrylate (DEMA), usi...
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| Veröffentlicht in: | Macromolecular rapid communications. 2017-08, Vol.38 (15), p.n/a |
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| creator | Huang, Jianbing Li, Decai Liang, Hui Lu, Jiang |
| description | Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization‐induced self‐assembly of a multifunctional core‐forming monomer, 2‐((3‐(4‐(diethylamino)phenyl)acryloyl)oxy)ethyl methacrylate (DEMA), using poly(2‐hydroxypropyl methacrylate) macromolecular chain transfer agent as a steric stabilizer in methanol at 65 °C. By tuning the chain length of PDEMA, a range of nanoparticle morphologies (sphere, worm, and vesicle) can be obtained. Since cinnamate groups can easily undergo a [2 + 2] cycloaddition of the carbon–carbon double bonds upon UV irradiation, the as‐prepared block copolymer nanoparticles are readily stabilized by photo‐crosslinking to produce anisotropic nanoparticles. The crosslinked block copolymer nanoparticles can be used as templates for in situ formation polymer/gold hybrid nanoparticles.
Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via RAFT‐polymerization‐induced self‐assembly and stabilized by photo‐crosslinking. The crosslinked block copolymer nanoparticles can be used as stable templates for in situ formation of polymer/gold hybrid nanoparticles. |
| doi_str_mv | 10.1002/marc.201700202 |
| format | Article |
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Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via RAFT‐polymerization‐induced self‐assembly and stabilized by photo‐crosslinking. The crosslinked block copolymer nanoparticles can be used as stable templates for in situ formation of polymer/gold hybrid nanoparticles.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.201700202</identifier><identifier>PMID: 28605150</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Addition polymerization ; Amines - chemistry ; Block copolymers ; Carbon cycle ; Chain transfer ; Chains (polymeric) ; Chemical synthesis ; Chemistry Techniques, Analytical ; Copolymers ; Crosslinking ; Cycloaddition ; Gold ; gold/polymer hybrids ; Hydroxypropyl methacrylate ; Irradiation ; Macromolecules ; Methacrylates - chemistry ; Methanol ; multifunctional ; Nanoparticles ; Nanoparticles - chemistry ; photo‐crosslinkable ; Polymerization ; polymerization‐induced self‐assembly ; Self-assembly ; Ultraviolet radiation ; Ultraviolet Rays</subject><ispartof>Macromolecular rapid communications., 2017-08, Vol.38 (15), p.n/a</ispartof><rights>2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4392-9b4846ad7e12a1c62defb29d20af25f5f97cacaf17f6786f33a3143a416790a13</citedby><cites>FETCH-LOGICAL-c4392-9b4846ad7e12a1c62defb29d20af25f5f97cacaf17f6786f33a3143a416790a13</cites><orcidid>0000-0002-8611-3828</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fmarc.201700202$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fmarc.201700202$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27907,27908,45557,45558</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28605150$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Huang, Jianbing</creatorcontrib><creatorcontrib>Li, Decai</creatorcontrib><creatorcontrib>Liang, Hui</creatorcontrib><creatorcontrib>Lu, Jiang</creatorcontrib><title>Synthesis of Photocrosslinkable and Amine Containing Multifunctional Nanoparticles via Polymerization‐Induced Self‐Assembly</title><title>Macromolecular rapid communications.</title><addtitle>Macromol Rapid Commun</addtitle><description>Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization‐induced self‐assembly of a multifunctional core‐forming monomer, 2‐((3‐(4‐(diethylamino)phenyl)acryloyl)oxy)ethyl methacrylate (DEMA), using poly(2‐hydroxypropyl methacrylate) macromolecular chain transfer agent as a steric stabilizer in methanol at 65 °C. By tuning the chain length of PDEMA, a range of nanoparticle morphologies (sphere, worm, and vesicle) can be obtained. Since cinnamate groups can easily undergo a [2 + 2] cycloaddition of the carbon–carbon double bonds upon UV irradiation, the as‐prepared block copolymer nanoparticles are readily stabilized by photo‐crosslinking to produce anisotropic nanoparticles. The crosslinked block copolymer nanoparticles can be used as templates for in situ formation polymer/gold hybrid nanoparticles.
Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via RAFT‐polymerization‐induced self‐assembly and stabilized by photo‐crosslinking. The crosslinked block copolymer nanoparticles can be used as stable templates for in situ formation of polymer/gold hybrid nanoparticles.</description><subject>Addition polymerization</subject><subject>Amines - chemistry</subject><subject>Block copolymers</subject><subject>Carbon cycle</subject><subject>Chain transfer</subject><subject>Chains (polymeric)</subject><subject>Chemical synthesis</subject><subject>Chemistry Techniques, Analytical</subject><subject>Copolymers</subject><subject>Crosslinking</subject><subject>Cycloaddition</subject><subject>Gold</subject><subject>gold/polymer hybrids</subject><subject>Hydroxypropyl methacrylate</subject><subject>Irradiation</subject><subject>Macromolecules</subject><subject>Methacrylates - chemistry</subject><subject>Methanol</subject><subject>multifunctional</subject><subject>Nanoparticles</subject><subject>Nanoparticles - chemistry</subject><subject>photo‐crosslinkable</subject><subject>Polymerization</subject><subject>polymerization‐induced self‐assembly</subject><subject>Self-assembly</subject><subject>Ultraviolet radiation</subject><subject>Ultraviolet Rays</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkU1v1DAQhi0E6veVI7LEhUsWfyRxclytSluphYrCOZo4Y-ri2EuctEov8BP4jfwSvGwpEpeeZkZ65pVmHkJecrbgjIm3PQx6IRhXaWDiGdnjheCZrIV6nnomRMalLHfJfow3jLEqZ2KH7IqqZAUv2B75fjX78RqjjTQYenkdxqCHEKOz_iu0Din4ji5765Gugh_Beuu_0IvJjdZMXo82eHD0PfiwhmG02mGktxboZXBzj4O9hw3y68fPM99NGjt6hc6kcRkj9q2bD8kLAy7i0UM9IJ_fHX9anWbnH07OVsvzTOfpmKxu8yovoVPIBXBdig5NK-pOMDCiMIWplQYNhitTqqo0UoLkuYScl6pmwOUBebPNXQ_h24RxbHobNToHHsMUG16zStWKFTKhr_9Db8I0pDM3lCjS34SqErXYUn_eNaBp1oNNNuaGs2ajptmoaR7VpIVXD7FT22P3iP91kYB6C9xZh_MTcc3F8uPqX_hvTc-e4w</recordid><startdate>201708</startdate><enddate>201708</enddate><creator>Huang, Jianbing</creator><creator>Li, Decai</creator><creator>Liang, Hui</creator><creator>Lu, Jiang</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>JQ2</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-8611-3828</orcidid></search><sort><creationdate>201708</creationdate><title>Synthesis of Photocrosslinkable and Amine Containing Multifunctional Nanoparticles via Polymerization‐Induced Self‐Assembly</title><author>Huang, Jianbing ; Li, Decai ; Liang, Hui ; Lu, Jiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4392-9b4846ad7e12a1c62defb29d20af25f5f97cacaf17f6786f33a3143a416790a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Addition polymerization</topic><topic>Amines - chemistry</topic><topic>Block copolymers</topic><topic>Carbon cycle</topic><topic>Chain transfer</topic><topic>Chains (polymeric)</topic><topic>Chemical synthesis</topic><topic>Chemistry Techniques, Analytical</topic><topic>Copolymers</topic><topic>Crosslinking</topic><topic>Cycloaddition</topic><topic>Gold</topic><topic>gold/polymer hybrids</topic><topic>Hydroxypropyl methacrylate</topic><topic>Irradiation</topic><topic>Macromolecules</topic><topic>Methacrylates - chemistry</topic><topic>Methanol</topic><topic>multifunctional</topic><topic>Nanoparticles</topic><topic>Nanoparticles - chemistry</topic><topic>photo‐crosslinkable</topic><topic>Polymerization</topic><topic>polymerization‐induced self‐assembly</topic><topic>Self-assembly</topic><topic>Ultraviolet radiation</topic><topic>Ultraviolet Rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Jianbing</creatorcontrib><creatorcontrib>Li, Decai</creatorcontrib><creatorcontrib>Liang, Hui</creatorcontrib><creatorcontrib>Lu, Jiang</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Jianbing</au><au>Li, Decai</au><au>Liang, Hui</au><au>Lu, Jiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Photocrosslinkable and Amine Containing Multifunctional Nanoparticles via Polymerization‐Induced Self‐Assembly</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol Rapid Commun</addtitle><date>2017-08</date><risdate>2017</risdate><volume>38</volume><issue>15</issue><epage>n/a</epage><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization‐induced self‐assembly of a multifunctional core‐forming monomer, 2‐((3‐(4‐(diethylamino)phenyl)acryloyl)oxy)ethyl methacrylate (DEMA), using poly(2‐hydroxypropyl methacrylate) macromolecular chain transfer agent as a steric stabilizer in methanol at 65 °C. By tuning the chain length of PDEMA, a range of nanoparticle morphologies (sphere, worm, and vesicle) can be obtained. Since cinnamate groups can easily undergo a [2 + 2] cycloaddition of the carbon–carbon double bonds upon UV irradiation, the as‐prepared block copolymer nanoparticles are readily stabilized by photo‐crosslinking to produce anisotropic nanoparticles. The crosslinked block copolymer nanoparticles can be used as templates for in situ formation polymer/gold hybrid nanoparticles.
Photo‐crosslinkable and amine‐containing block copolymer nanoparticles are synthesized via RAFT‐polymerization‐induced self‐assembly and stabilized by photo‐crosslinking. The crosslinked block copolymer nanoparticles can be used as stable templates for in situ formation of polymer/gold hybrid nanoparticles.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>28605150</pmid><doi>10.1002/marc.201700202</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-8611-3828</orcidid></addata></record> |
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| subjects | Addition polymerization Amines - chemistry Block copolymers Carbon cycle Chain transfer Chains (polymeric) Chemical synthesis Chemistry Techniques, Analytical Copolymers Crosslinking Cycloaddition Gold gold/polymer hybrids Hydroxypropyl methacrylate Irradiation Macromolecules Methacrylates - chemistry Methanol multifunctional Nanoparticles Nanoparticles - chemistry photo‐crosslinkable Polymerization polymerization‐induced self‐assembly Self-assembly Ultraviolet radiation Ultraviolet Rays |
| title | Synthesis of Photocrosslinkable and Amine Containing Multifunctional Nanoparticles via Polymerization‐Induced Self‐Assembly |
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