Denitrogenative Imidoyl Radical Cyclization: Synthesis of 2‑Substituted Benzoimidazoles from 1‑Azido-2-isocyanoarenes

A novel access to 2-substituted benzoimidazoles, through unprecedented denitrogenative imidoyl radical cyclization of 1-azido-2-isocyanoarenes, has been developed. This tandem radical process was initiated by adding a C- or P-centered radical to isocyanide, followed by cycloaddition of the imidoyl r...

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Veröffentlicht in:	Organic letters 2017-06, Vol.19 (12), p.3223-3226
Hauptverfasser:	Li, Dengke, Mao, Tingting, Huang, Jinbo, Zhu, Qiang
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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