Synthesis and Characterization of a Metallacyclic Framework with Three Fused Five‐membered Rings

Polycyclic complexes containing a bridgehead transition metal are interesting species because the transition metal is shared by all the rings simultaneously. In this study, we present a novel osmium–bridgehead system with three fused five‐membered rings. This novel framework can be viewed as a 10‐at...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-07, Vol.56 (31), p.9067-9071
Hauptverfasser:	Zhu, Congqing, Wu, Jingjing, Li, Shenyan, Yang, Yuhui, Zhu, Jun, Lu, Xin, Xia, Haiping
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption spectra Aromaticity DFT calculations metallacycles metallapentalene Metals Osmium X-ray diffraction X-rays
Online-Zugang:	Volltext
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