Fighting Fenton Chemistry: A Highly Active Iron(III) Tetracarbene Complex in Epoxidation Catalysis

Organometallic Fe complexes with exceptionally high activities in homogeneous epoxidation catalysis are reported. The compounds display FeII and FeIII oxidation states and bear a tetracarbene ligand. The more active catalyst exhibits activities up to 183 000 turnovers per hour at room temperature an...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	ChemSusChem 2015-12, Vol.8 (23), p.4056-4063
Hauptverfasser:	Kück, Jens W., Anneser, Markus R., Hofmann, Benjamin, Pöthig, Alexander, Cokoja, Mirza, Kühn, Fritz E.
Format:	Artikel
Sprache:	eng
Schlagworte:	carbene ligands Catalysis epoxidation Epoxy Compounds - chemistry Heterocyclic Compounds - chemistry homogeneous catalysis Hydroxylation iron Iron - chemistry Methane - analogs & derivatives Methane - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry peroxides
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!