Hollow carbon nanobubbles: monocrystalline MOF nanobubbles and their pyrolysis
While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nanoarchitectonics is believed to be a possible solution. It is highly challenging to realize MOF nanobubbles with monocrystalline frameworks. By a spatia...
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| Veröffentlicht in: | Chemical science (Cambridge) 2017-05, Vol.8 (5), p.3538-3546 |
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| creator | Zhang, Wei Jiang, Xiangfen Zhao, Yanyi Carné-Sánchez, Arnau Malgras, Victor Kim, Jeonghun Kim, Jung Ho Wang, Shaobin Liu, Jian Jiang, Ji-Sen Yamauchi, Yusuke Hu, Ming |
| description | While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nanoarchitectonics is believed to be a possible solution. It is highly challenging to realize MOF nanobubbles with monocrystalline frameworks. By a spatially controlled etching approach, here, we can achieve the synthesis of zeolitic imidazolate framework (ZIF-8) nanobubbles with a uniform size of less than 100 nm. Interestingly, the ZIF-8 nanobubbles possess a monocrystalline nanoshell with a thickness of around 10 nm. Under optimal pyrolytic conditions, the ZIF-8 nanobubbles can be converted into hollow carbon nanobubbles while keeping their original shapes. The structure of the nanobubble enhances the fast Na
/K
ion intercalation performance. Such remarkable improvement cannot be realized by conventional MOFs or their derived carbons. |
| doi_str_mv | 10.1039/c6sc04903f |
| format | Article |
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/K
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/K
ion intercalation performance. Such remarkable improvement cannot be realized by conventional MOFs or their derived carbons.</description><subject>Carbon</subject><subject>Chemistry</subject><subject>Energy storage</subject><subject>Etching</subject><subject>Metal-organic frameworks</subject><subject>Nanostructure</subject><subject>Optimization</subject><subject>Pyrolysis</subject><subject>Synthesis</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNkU9LAzEQxYMottRe_ACyRxGq-b9ZD4Is1grVHtRzyKaJXckmNdkq_fauVku9OZcZmB9v3vAAOEbwHEFSXGieNKQFJHYP9DGkaMQZKfa3M4Y9MEzpFXZFCGI4PwQ9LJiAsBB98DAJzoWPTKtYBZ955UO1qipn0mXWBB90XKdWOVd7k93PxrtApvw8axemjtlyHYNbpzodgQOrXDLDnz4Az-Obp3Iyms5u78rr6UgzjNoR13xuLWNaWMTIPKe2YoUgVlFIVI41syRHQgjEObIKwsoSjoRCSCusjVZkAK42ustV1Zi5Nr6NysllrBsV1zKoWv7d-HohX8K7ZJRw3J0agNMfgRjeVia1sqmTNs4pb8IqSVRAjijrLPwHpZhiBnmHnm1QHUNK0ditIwTlV1yy5I_ld1zjDj7Z_WGL_oZDPgEmBJEr</recordid><startdate>20170501</startdate><enddate>20170501</enddate><creator>Zhang, Wei</creator><creator>Jiang, Xiangfen</creator><creator>Zhao, Yanyi</creator><creator>Carné-Sánchez, Arnau</creator><creator>Malgras, Victor</creator><creator>Kim, Jeonghun</creator><creator>Kim, Jung Ho</creator><creator>Wang, Shaobin</creator><creator>Liu, Jian</creator><creator>Jiang, Ji-Sen</creator><creator>Yamauchi, Yusuke</creator><creator>Hu, Ming</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-5667-9118</orcidid><orcidid>https://orcid.org/0000-0002-5114-0404</orcidid><orcidid>https://orcid.org/0000-0002-5024-5650</orcidid><orcidid>https://orcid.org/0000-0002-1751-9162</orcidid><orcidid>https://orcid.org/0000-0001-7854-927X</orcidid></search><sort><creationdate>20170501</creationdate><title>Hollow carbon nanobubbles: monocrystalline MOF nanobubbles and their pyrolysis</title><author>Zhang, Wei ; Jiang, Xiangfen ; Zhao, Yanyi ; Carné-Sánchez, Arnau ; Malgras, Victor ; Kim, Jeonghun ; Kim, Jung Ho ; Wang, Shaobin ; Liu, Jian ; Jiang, Ji-Sen ; Yamauchi, Yusuke ; Hu, Ming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c521t-6c6dff55c8f153d74fb5983fa403a72c5f3718881661fa00bf3618a11ca2ceca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Carbon</topic><topic>Chemistry</topic><topic>Energy storage</topic><topic>Etching</topic><topic>Metal-organic frameworks</topic><topic>Nanostructure</topic><topic>Optimization</topic><topic>Pyrolysis</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Wei</creatorcontrib><creatorcontrib>Jiang, Xiangfen</creatorcontrib><creatorcontrib>Zhao, Yanyi</creatorcontrib><creatorcontrib>Carné-Sánchez, Arnau</creatorcontrib><creatorcontrib>Malgras, Victor</creatorcontrib><creatorcontrib>Kim, Jeonghun</creatorcontrib><creatorcontrib>Kim, Jung Ho</creatorcontrib><creatorcontrib>Wang, Shaobin</creatorcontrib><creatorcontrib>Liu, Jian</creatorcontrib><creatorcontrib>Jiang, Ji-Sen</creatorcontrib><creatorcontrib>Yamauchi, Yusuke</creatorcontrib><creatorcontrib>Hu, Ming</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Wei</au><au>Jiang, Xiangfen</au><au>Zhao, Yanyi</au><au>Carné-Sánchez, Arnau</au><au>Malgras, Victor</au><au>Kim, Jeonghun</au><au>Kim, Jung Ho</au><au>Wang, Shaobin</au><au>Liu, Jian</au><au>Jiang, Ji-Sen</au><au>Yamauchi, Yusuke</au><au>Hu, Ming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hollow carbon nanobubbles: monocrystalline MOF nanobubbles and their pyrolysis</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2017-05-01</date><risdate>2017</risdate><volume>8</volume><issue>5</issue><spage>3538</spage><epage>3546</epage><pages>3538-3546</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>While bulk-sized metal-organic frameworks (MOFs) face limits to their utilization in various research fields such as energy storage applications, nanoarchitectonics is believed to be a possible solution. 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/K
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| source | DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals; PubMed Central; PubMed Central Open Access |
| subjects | Carbon Chemistry Energy storage Etching Metal-organic frameworks Nanostructure Optimization Pyrolysis Synthesis |
| title | Hollow carbon nanobubbles: monocrystalline MOF nanobubbles and their pyrolysis |
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