Uncatalyzed Carboboration of Seven-Membered-Ring trans-Alkenes: Formation of Air-Stable Trialkylboranes

Seven-membered-ring trans-alkenes undergo rapid, uncatalyzed carboboration reactions to form trialkylboranes as single diastereomers. In contrast with other trialkylboranes, which can ignite in the presence of oxygen, these trialkylboranes are stable in air. Hindered trialkylboranes can undergo reve...

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Veröffentlicht in:	Journal of the American Chemical Society 2017-06, Vol.139 (25), p.8404-8407
Hauptverfasser:	Sanzone, Jillian R, Hu, Chunhua T, Woerpel, K. A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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