Topochemical synthesis of cation ordered double perovskite oxynitrides
Topochemical nitridation in ammonia at moderate temperatures of cation ordered Sr FeWO produces new antiferromagnetic double perovskite oxynitrides Sr FeWO N with 0 < x ≤ 1. Nitrogen introduction induces the oxidation of Fe to Fe and decreases T from 38 K (x = 0) to 13 K for Sr FeWO N which repre...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2017, Vol.46 (16), p.5128-5132 |
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| container_issue | 16 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 46 |
| creator | Ceravola, Roberta Oró-Solé, Judith Black, Ashley P Ritter, Clemens Puente Orench, Inés Mata, Ignasi Molins, Elies Frontera, Carlos Fuertes, Amparo |
| description | Topochemical nitridation in ammonia at moderate temperatures of cation ordered Sr
FeWO
produces new antiferromagnetic double perovskite oxynitrides Sr
FeWO
N
with 0 < x ≤ 1. Nitrogen introduction induces the oxidation of Fe
to Fe
and decreases T
from 38 K (x = 0) to 13 K for Sr
FeWO
N which represents the first example of a double perovskite oxynitride with both high cationic order and nitrogen content. This synthetic approach can be extended to other cation combinations expanding the possibility of new materials in the large group of double perovskites. |
| doi_str_mv | 10.1039/c7dt00800g |
| format | Article |
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FeWO
produces new antiferromagnetic double perovskite oxynitrides Sr
FeWO
N
with 0 < x ≤ 1. Nitrogen introduction induces the oxidation of Fe
to Fe
and decreases T
from 38 K (x = 0) to 13 K for Sr
FeWO
N which represents the first example of a double perovskite oxynitride with both high cationic order and nitrogen content. This synthetic approach can be extended to other cation combinations expanding the possibility of new materials in the large group of double perovskites.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt00800g</identifier><identifier>PMID: 28345706</identifier><language>eng</language><publisher>England</publisher><subject>Ammonia ; Antiferromagnetism ; Cationic ; Cations ; Nitrogen ; Oxynitrides ; Perovskites ; Synthesis</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2017, Vol.46 (16), p.5128-5132</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-796831b81e285a83ff918956849cf5f9af0c96253061cb868321968771fd7a1c3</citedby><cites>FETCH-LOGICAL-c386t-796831b81e285a83ff918956849cf5f9af0c96253061cb868321968771fd7a1c3</cites><orcidid>0000-0001-5338-9724 ; 0000-0002-4835-9659</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,4010,27904,27905,27906</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28345706$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ceravola, Roberta</creatorcontrib><creatorcontrib>Oró-Solé, Judith</creatorcontrib><creatorcontrib>Black, Ashley P</creatorcontrib><creatorcontrib>Ritter, Clemens</creatorcontrib><creatorcontrib>Puente Orench, Inés</creatorcontrib><creatorcontrib>Mata, Ignasi</creatorcontrib><creatorcontrib>Molins, Elies</creatorcontrib><creatorcontrib>Frontera, Carlos</creatorcontrib><creatorcontrib>Fuertes, Amparo</creatorcontrib><title>Topochemical synthesis of cation ordered double perovskite oxynitrides</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Topochemical nitridation in ammonia at moderate temperatures of cation ordered Sr
FeWO
produces new antiferromagnetic double perovskite oxynitrides Sr
FeWO
N
with 0 < x ≤ 1. Nitrogen introduction induces the oxidation of Fe
to Fe
and decreases T
from 38 K (x = 0) to 13 K for Sr
FeWO
N which represents the first example of a double perovskite oxynitride with both high cationic order and nitrogen content. This synthetic approach can be extended to other cation combinations expanding the possibility of new materials in the large group of double perovskites.</description><subject>Ammonia</subject><subject>Antiferromagnetism</subject><subject>Cationic</subject><subject>Cations</subject><subject>Nitrogen</subject><subject>Oxynitrides</subject><subject>Perovskites</subject><subject>Synthesis</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqF0L1OwzAUBWALgWgpLDwAyoiQAv5LfD2iQgtSJZYyR45jU0MSBztB9O0JtLAy3Tt85wwHoXOCrwlm8kaLqscYMH45QFPChUglZfzw76f5BJ3E-IoxpTijx2hCgfFM4HyKFmvfeb0xjdOqTuK27Tcmuph4m2jVO98mPlQmmCqp_FDWJulM8B_xzfUm8Z_b1vXBVSaeoiOr6mjO9neGnhf36_lDunpaPs5vV6lmkPepkDkwUgIxFDIFzFpJQGY5cKltZqWyWMucZgznRJcwYkrGiBDEVkIRzWboctfbBf8-mNgXjYva1LVqjR9iQSTmlIMA-J8CEM6ByGykVzuqg48xGFt0wTUqbAuCi--Ji7m4W_9MvBzxxb53KBtT_dHfTdkXhZB1pw</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Ceravola, Roberta</creator><creator>Oró-Solé, Judith</creator><creator>Black, Ashley P</creator><creator>Ritter, Clemens</creator><creator>Puente Orench, Inés</creator><creator>Mata, Ignasi</creator><creator>Molins, Elies</creator><creator>Frontera, Carlos</creator><creator>Fuertes, Amparo</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-5338-9724</orcidid><orcidid>https://orcid.org/0000-0002-4835-9659</orcidid></search><sort><creationdate>2017</creationdate><title>Topochemical synthesis of cation ordered double perovskite oxynitrides</title><author>Ceravola, Roberta ; Oró-Solé, Judith ; Black, Ashley P ; Ritter, Clemens ; Puente Orench, Inés ; Mata, Ignasi ; Molins, Elies ; Frontera, Carlos ; Fuertes, Amparo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-796831b81e285a83ff918956849cf5f9af0c96253061cb868321968771fd7a1c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Ammonia</topic><topic>Antiferromagnetism</topic><topic>Cationic</topic><topic>Cations</topic><topic>Nitrogen</topic><topic>Oxynitrides</topic><topic>Perovskites</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ceravola, Roberta</creatorcontrib><creatorcontrib>Oró-Solé, Judith</creatorcontrib><creatorcontrib>Black, Ashley P</creatorcontrib><creatorcontrib>Ritter, Clemens</creatorcontrib><creatorcontrib>Puente Orench, Inés</creatorcontrib><creatorcontrib>Mata, Ignasi</creatorcontrib><creatorcontrib>Molins, Elies</creatorcontrib><creatorcontrib>Frontera, Carlos</creatorcontrib><creatorcontrib>Fuertes, Amparo</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ceravola, Roberta</au><au>Oró-Solé, Judith</au><au>Black, Ashley P</au><au>Ritter, Clemens</au><au>Puente Orench, Inés</au><au>Mata, Ignasi</au><au>Molins, Elies</au><au>Frontera, Carlos</au><au>Fuertes, Amparo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Topochemical synthesis of cation ordered double perovskite oxynitrides</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2017</date><risdate>2017</risdate><volume>46</volume><issue>16</issue><spage>5128</spage><epage>5132</epage><pages>5128-5132</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Topochemical nitridation in ammonia at moderate temperatures of cation ordered Sr
FeWO
produces new antiferromagnetic double perovskite oxynitrides Sr
FeWO
N
with 0 < x ≤ 1. Nitrogen introduction induces the oxidation of Fe
to Fe
and decreases T
from 38 K (x = 0) to 13 K for Sr
FeWO
N which represents the first example of a double perovskite oxynitride with both high cationic order and nitrogen content. This synthetic approach can be extended to other cation combinations expanding the possibility of new materials in the large group of double perovskites.</abstract><cop>England</cop><pmid>28345706</pmid><doi>10.1039/c7dt00800g</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-5338-9724</orcidid><orcidid>https://orcid.org/0000-0002-4835-9659</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2017, Vol.46 (16), p.5128-5132 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1904248788 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ammonia Antiferromagnetism Cationic Cations Nitrogen Oxynitrides Perovskites Synthesis |
| title | Topochemical synthesis of cation ordered double perovskite oxynitrides |
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