Photo-induced structural modification of silk gels containing azobenzene side groups

Azobenzene modification of Bombyx mori silkworm silk creates a photo-responsive 'azosilk' biomaterial, allowing for 3D laser patterning. Written regions fluoresce, and become fluid-filled raised 'micro-blisters' with a 10-fold photo-softening effect of the modulus. Patterning is...

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Veröffentlicht in:Soft matter 2017, Vol.13 (16), p.2903-2906
Hauptverfasser: Landry, Michael J, Applegate, Matthew B, Bushuyev, Oleksandr S, Omenetto, Fiorenzo G, Kaplan, David L, Cronin-Golomb, Mark, Barrett, Christopher J
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Sprache:eng
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Zusammenfassung:Azobenzene modification of Bombyx mori silkworm silk creates a photo-responsive 'azosilk' biomaterial, allowing for 3D laser patterning. Written regions fluoresce, and become fluid-filled raised 'micro-blisters' with a 10-fold photo-softening effect of the modulus. Patterning is facile and versatile, with potential applications as soft tunable materials for dynamic cell guidance and microfluidics.
ISSN:1744-683X
1744-6848
DOI:10.1039/c7sm00446j