Mono- and Hetero-Dinuclear Complexes of Janus-Head NHC Ligands Possessing Backbone Phosphinoyl Groups: the Case of Soft and Hard Metal Centers

The synthesis and structures of RhI and IrI complexes bearing 4‐phosphinoyl‐ and 4,5‐bis(phosphinoyl)imidazol‐2‐ylidene ligands (NHCP) is reported. Deprotonation of the corresponding imidazolium hydrogen sulfate salts by KOtBu in the presence of [M(cod)Cl]2 afforded complexes of the formula [M(cod)C...

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Veröffentlicht in:	European journal of inorganic chemistry 2014-10, Vol.2014 (29), p.4975-4983
Hauptverfasser:	Majhi, Paresh Kumar, Serin, Spencer C., Schnakenburg, Gregor, Gates, Derek P., Streubel, Rainer
Format:	Artikel
Sprache:	eng
Schlagworte:	Backbone Carbene li­gands Carbon monoxide Coordination compounds Hydrogen Iridium Ligand design Ligands Nitrogen heterocycles Phosphine oxide Rhodium Sulfates Synthesis
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