Vibrational relaxation and microsolvation of DF after F-atom reactions in polar solvents

Solvent-solute interactions influence the mechanisms of chemical reactions in solution, but the response of the solvent is often slower than the reactive event. Here, we report that exothermic reactions of fluorine (F) atoms in d3-acetonitrile and d2-dichloromethane involve efficient energy flow to...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2015-01, Vol.347 (6221), p.530-533
Hauptverfasser:	Dunning, G. T., Glowacki, D. R., Preston, T. J., Greaves, S. J., Greetham, G. M., Clark, I. P., Towrie, M., Harvey, J. N., Orr-Ewing, A. J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atoms & subatomic particles Chemical reactions Chemistry Deuterium fluorides Dissipation Dynamics Gas phases Infrared absorption Inhalants Organic Chemistry Solution chemistry Solvents Spectroscopy Vibration
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