Comparative solution equilibrium studies of antitumor ruthenium(η 6 -p-cymene) and rhodium(η 5 -C 5 Me 5 ) complexes of 8-hydroxyquinolines

Complex formation processes of [Ru(η -p-cymene)(H O) ] and [Rh(η -C Me )(H O) ] organometallic cations with 8-hydroxyquinoline (HQ) ligands were studied in aqueous solution by the combined use of H NMR spectroscopy, UV-visible spectrophotometry and pH-potentiometry. Solution stability, chloride ion...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2017-03, Vol.46 (13), p.4382-4396
Hauptverfasser:	Dömötör, Orsolya, Pape, Veronika F S, May, Nóra V, Szakács, Gergely, Enyedy, Éva A
Format:	Artikel
Sprache:	eng
Schlagworte:	Antineoplastic Agents - chemical synthesis Antineoplastic Agents - chemistry Antineoplastic Agents - pharmacology Biotechnology Cancer Cell Line, Tumor Cell Survival - drug effects Chlorides - chemistry Coordination Complexes - chemical synthesis Coordination Complexes - chemistry Coordination Complexes - pharmacology Cyclopentanes - chemistry Drug Discovery Formations Humans Ligands Mathematical models Metalorganic compounds Monoterpenes - chemistry Organometallic Compounds Oxyquinoline - chemistry Piperidines - chemistry Rhodium - chemistry Ruthenium - chemistry Stability Sulfonic Acids - chemistry Toxicity Water - chemistry
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