Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran over Heterogeneous Iron Catalysts
This work provided the first example of selective hydrodeoxygenation of 5‐hydroxymethylfurfural (HMF) to 2,5‐dimethylfuran (DMF) over heterogeneous Fe catalysts. A catalyst prepared by the pyrolysis of an Fe‐phenanthroline complex on activated carbon at 800 °C was demonstrated to be the most active...
Gespeichert in:
| Veröffentlicht in: | ChemSusChem 2017-04, Vol.10 (7), p.1436-1447 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1447 |
|---|---|
| container_issue | 7 |
| container_start_page | 1436 |
| container_title | ChemSusChem |
| container_volume | 10 |
| creator | Li, Jiang Liu, Jun‐ling Liu, He‐yang Xu, Guang‐yue Zhang, Jun‐jie Liu, Jia‐xing Zhou, Guang‐lin Li, Qin Xu, Zhi‐hao Fu, Yao |
| description | This work provided the first example of selective hydrodeoxygenation of 5‐hydroxymethylfurfural (HMF) to 2,5‐dimethylfuran (DMF) over heterogeneous Fe catalysts. A catalyst prepared by the pyrolysis of an Fe‐phenanthroline complex on activated carbon at 800 °C was demonstrated to be the most active heterogeneous Fe catalyst. Under the optimal reaction conditions, complete conversion of HMF was achieved with 86.2 % selectivity to DMF. The reaction pathway was investigated thoroughly, and the hydrogenation of the C=O bond in HMF was demonstrated to be the rate‐determining step during the hydrodeoxygenation, which could be accelerated greatly by using alcohol solvents as additional H‐donors. The excellent stability of the Fe catalyst, which was probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2, was demonstrated in batch and continuous flow fixed‐bed reactors.
Selective and stable Fe: Selective catalytic hydrodeoxygenation of 5‐hydroxymethylfurfural to 2,5‐dimethylfuran over heterogeneous Fe catalysts is demonstrated in batch and continuous flow fixed‐bed reactors. The Fe catalyst exhibited excellent stability, which is probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2. |
| doi_str_mv | 10.1002/cssc.201700105 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1904215432</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4321599271</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4765-20e2e15ffd5be7a3d5c768e8144bda1b95b90f3fb882e8444db199cefaf69c823</originalsourceid><addsrcrecordid>eNqNkUFLHDEYhkNpqbrt1aMM9NKDu00ySSY5yrS6woKHbaG3kMl80ZHZjSYzW-fmT_A3-kvM7toVvCgEEnif7-ELL0KHBE8IxvSHjdFOKCYFxgTzD2ifSMHGXLC_H3fvnOyhgxivMRZYCfEZ7VFJBGa52kdhDi3YrllBNh3q4Gvwd8MlLE3X-GXmXcYf7x82yd2wgO5qaF0f0jFt1vmMHq_jn80uMWlmBSGbQgfBJw_4PmbnIblK05l2iF38gj4500b4-nyP0J_TX7_L6Xh2cXZenszGlhWCjykGCoQ7V_MKCpPX3BZCgiSMVbUhleKVwi53lZQUJGOsrohSFpxxQllJ8xH6vvXeBH_bQ-z0ookW2tZsttJEYUYJZ_k7UKmIlIJI_g5UcJ4rLnFCv71Cr30flunPemNTBZdFoiZbygYfYwCnb0KzMGHQBOt1x3rdsd51nAaOnrV9tYB6h_8vNQFqC_xrWhje0OlyPi9f5E87-LZV</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1886197587</pqid></control><display><type>article</type><title>Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran over Heterogeneous Iron Catalysts</title><source>MEDLINE</source><source>Access via Wiley Online Library</source><creator>Li, Jiang ; Liu, Jun‐ling ; Liu, He‐yang ; Xu, Guang‐yue ; Zhang, Jun‐jie ; Liu, Jia‐xing ; Zhou, Guang‐lin ; Li, Qin ; Xu, Zhi‐hao ; Fu, Yao</creator><creatorcontrib>Li, Jiang ; Liu, Jun‐ling ; Liu, He‐yang ; Xu, Guang‐yue ; Zhang, Jun‐jie ; Liu, Jia‐xing ; Zhou, Guang‐lin ; Li, Qin ; Xu, Zhi‐hao ; Fu, Yao</creatorcontrib><description>This work provided the first example of selective hydrodeoxygenation of 5‐hydroxymethylfurfural (HMF) to 2,5‐dimethylfuran (DMF) over heterogeneous Fe catalysts. A catalyst prepared by the pyrolysis of an Fe‐phenanthroline complex on activated carbon at 800 °C was demonstrated to be the most active heterogeneous Fe catalyst. Under the optimal reaction conditions, complete conversion of HMF was achieved with 86.2 % selectivity to DMF. The reaction pathway was investigated thoroughly, and the hydrogenation of the C=O bond in HMF was demonstrated to be the rate‐determining step during the hydrodeoxygenation, which could be accelerated greatly by using alcohol solvents as additional H‐donors. The excellent stability of the Fe catalyst, which was probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2, was demonstrated in batch and continuous flow fixed‐bed reactors.
Selective and stable Fe: Selective catalytic hydrodeoxygenation of 5‐hydroxymethylfurfural to 2,5‐dimethylfuran over heterogeneous Fe catalysts is demonstrated in batch and continuous flow fixed‐bed reactors. The Fe catalyst exhibited excellent stability, which is probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201700105</identifier><identifier>PMID: 28160439</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>5-hydroxymethylfurfural ; biomass ; Catalysis ; Catalysts ; Continuous flow ; Furaldehyde - analogs & derivatives ; Furaldehyde - chemistry ; Furans - chemistry ; heterogeneous catalysis ; hydrodeoxygenation ; Hydrogen - chemistry ; Iron ; Iron - chemistry ; Oxygen - chemistry ; Porosity ; Pressure ; Pyrolysis ; Reactors ; Solvents - chemistry ; Structural stability ; Temperature</subject><ispartof>ChemSusChem, 2017-04, Vol.10 (7), p.1436-1447</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4765-20e2e15ffd5be7a3d5c768e8144bda1b95b90f3fb882e8444db199cefaf69c823</citedby><cites>FETCH-LOGICAL-c4765-20e2e15ffd5be7a3d5c768e8144bda1b95b90f3fb882e8444db199cefaf69c823</cites><orcidid>0000-0001-7132-5302</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.201700105$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.201700105$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27926,27927,45576,45577</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28160439$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Jiang</creatorcontrib><creatorcontrib>Liu, Jun‐ling</creatorcontrib><creatorcontrib>Liu, He‐yang</creatorcontrib><creatorcontrib>Xu, Guang‐yue</creatorcontrib><creatorcontrib>Zhang, Jun‐jie</creatorcontrib><creatorcontrib>Liu, Jia‐xing</creatorcontrib><creatorcontrib>Zhou, Guang‐lin</creatorcontrib><creatorcontrib>Li, Qin</creatorcontrib><creatorcontrib>Xu, Zhi‐hao</creatorcontrib><creatorcontrib>Fu, Yao</creatorcontrib><title>Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran over Heterogeneous Iron Catalysts</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>This work provided the first example of selective hydrodeoxygenation of 5‐hydroxymethylfurfural (HMF) to 2,5‐dimethylfuran (DMF) over heterogeneous Fe catalysts. A catalyst prepared by the pyrolysis of an Fe‐phenanthroline complex on activated carbon at 800 °C was demonstrated to be the most active heterogeneous Fe catalyst. Under the optimal reaction conditions, complete conversion of HMF was achieved with 86.2 % selectivity to DMF. The reaction pathway was investigated thoroughly, and the hydrogenation of the C=O bond in HMF was demonstrated to be the rate‐determining step during the hydrodeoxygenation, which could be accelerated greatly by using alcohol solvents as additional H‐donors. The excellent stability of the Fe catalyst, which was probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2, was demonstrated in batch and continuous flow fixed‐bed reactors.
Selective and stable Fe: Selective catalytic hydrodeoxygenation of 5‐hydroxymethylfurfural to 2,5‐dimethylfuran over heterogeneous Fe catalysts is demonstrated in batch and continuous flow fixed‐bed reactors. The Fe catalyst exhibited excellent stability, which is probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2.</description><subject>5-hydroxymethylfurfural</subject><subject>biomass</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Continuous flow</subject><subject>Furaldehyde - analogs & derivatives</subject><subject>Furaldehyde - chemistry</subject><subject>Furans - chemistry</subject><subject>heterogeneous catalysis</subject><subject>hydrodeoxygenation</subject><subject>Hydrogen - chemistry</subject><subject>Iron</subject><subject>Iron - chemistry</subject><subject>Oxygen - chemistry</subject><subject>Porosity</subject><subject>Pressure</subject><subject>Pyrolysis</subject><subject>Reactors</subject><subject>Solvents - chemistry</subject><subject>Structural stability</subject><subject>Temperature</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNkUFLHDEYhkNpqbrt1aMM9NKDu00ySSY5yrS6woKHbaG3kMl80ZHZjSYzW-fmT_A3-kvM7toVvCgEEnif7-ELL0KHBE8IxvSHjdFOKCYFxgTzD2ifSMHGXLC_H3fvnOyhgxivMRZYCfEZ7VFJBGa52kdhDi3YrllBNh3q4Gvwd8MlLE3X-GXmXcYf7x82yd2wgO5qaF0f0jFt1vmMHq_jn80uMWlmBSGbQgfBJw_4PmbnIblK05l2iF38gj4500b4-nyP0J_TX7_L6Xh2cXZenszGlhWCjykGCoQ7V_MKCpPX3BZCgiSMVbUhleKVwi53lZQUJGOsrohSFpxxQllJ8xH6vvXeBH_bQ-z0ookW2tZsttJEYUYJZ_k7UKmIlIJI_g5UcJ4rLnFCv71Cr30flunPemNTBZdFoiZbygYfYwCnb0KzMGHQBOt1x3rdsd51nAaOnrV9tYB6h_8vNQFqC_xrWhje0OlyPi9f5E87-LZV</recordid><startdate>20170410</startdate><enddate>20170410</enddate><creator>Li, Jiang</creator><creator>Liu, Jun‐ling</creator><creator>Liu, He‐yang</creator><creator>Xu, Guang‐yue</creator><creator>Zhang, Jun‐jie</creator><creator>Liu, Jia‐xing</creator><creator>Zhou, Guang‐lin</creator><creator>Li, Qin</creator><creator>Xu, Zhi‐hao</creator><creator>Fu, Yao</creator><general>Wiley Subscription Services, Inc</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope><orcidid>https://orcid.org/0000-0001-7132-5302</orcidid></search><sort><creationdate>20170410</creationdate><title>Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran over Heterogeneous Iron Catalysts</title><author>Li, Jiang ; Liu, Jun‐ling ; Liu, He‐yang ; Xu, Guang‐yue ; Zhang, Jun‐jie ; Liu, Jia‐xing ; Zhou, Guang‐lin ; Li, Qin ; Xu, Zhi‐hao ; Fu, Yao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4765-20e2e15ffd5be7a3d5c768e8144bda1b95b90f3fb882e8444db199cefaf69c823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>5-hydroxymethylfurfural</topic><topic>biomass</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Continuous flow</topic><topic>Furaldehyde - analogs & derivatives</topic><topic>Furaldehyde - chemistry</topic><topic>Furans - chemistry</topic><topic>heterogeneous catalysis</topic><topic>hydrodeoxygenation</topic><topic>Hydrogen - chemistry</topic><topic>Iron</topic><topic>Iron - chemistry</topic><topic>Oxygen - chemistry</topic><topic>Porosity</topic><topic>Pressure</topic><topic>Pyrolysis</topic><topic>Reactors</topic><topic>Solvents - chemistry</topic><topic>Structural stability</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Jiang</creatorcontrib><creatorcontrib>Liu, Jun‐ling</creatorcontrib><creatorcontrib>Liu, He‐yang</creatorcontrib><creatorcontrib>Xu, Guang‐yue</creatorcontrib><creatorcontrib>Zhang, Jun‐jie</creatorcontrib><creatorcontrib>Liu, Jia‐xing</creatorcontrib><creatorcontrib>Zhou, Guang‐lin</creatorcontrib><creatorcontrib>Li, Qin</creatorcontrib><creatorcontrib>Xu, Zhi‐hao</creatorcontrib><creatorcontrib>Fu, Yao</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Jiang</au><au>Liu, Jun‐ling</au><au>Liu, He‐yang</au><au>Xu, Guang‐yue</au><au>Zhang, Jun‐jie</au><au>Liu, Jia‐xing</au><au>Zhou, Guang‐lin</au><au>Li, Qin</au><au>Xu, Zhi‐hao</au><au>Fu, Yao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran over Heterogeneous Iron Catalysts</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2017-04-10</date><risdate>2017</risdate><volume>10</volume><issue>7</issue><spage>1436</spage><epage>1447</epage><pages>1436-1447</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>This work provided the first example of selective hydrodeoxygenation of 5‐hydroxymethylfurfural (HMF) to 2,5‐dimethylfuran (DMF) over heterogeneous Fe catalysts. A catalyst prepared by the pyrolysis of an Fe‐phenanthroline complex on activated carbon at 800 °C was demonstrated to be the most active heterogeneous Fe catalyst. Under the optimal reaction conditions, complete conversion of HMF was achieved with 86.2 % selectivity to DMF. The reaction pathway was investigated thoroughly, and the hydrogenation of the C=O bond in HMF was demonstrated to be the rate‐determining step during the hydrodeoxygenation, which could be accelerated greatly by using alcohol solvents as additional H‐donors. The excellent stability of the Fe catalyst, which was probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2, was demonstrated in batch and continuous flow fixed‐bed reactors.
Selective and stable Fe: Selective catalytic hydrodeoxygenation of 5‐hydroxymethylfurfural to 2,5‐dimethylfuran over heterogeneous Fe catalysts is demonstrated in batch and continuous flow fixed‐bed reactors. The Fe catalyst exhibited excellent stability, which is probably a result of the well‐preserved active species and the pore structure of the Fe catalyst in the presence of H2.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>28160439</pmid><doi>10.1002/cssc.201700105</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-7132-5302</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1864-5631 |
| ispartof | ChemSusChem, 2017-04, Vol.10 (7), p.1436-1447 |
| issn | 1864-5631 1864-564X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1904215432 |
| source | MEDLINE; Access via Wiley Online Library |
| subjects | 5-hydroxymethylfurfural biomass Catalysis Catalysts Continuous flow Furaldehyde - analogs & derivatives Furaldehyde - chemistry Furans - chemistry heterogeneous catalysis hydrodeoxygenation Hydrogen - chemistry Iron Iron - chemistry Oxygen - chemistry Porosity Pressure Pyrolysis Reactors Solvents - chemistry Structural stability Temperature |
| title | Selective Hydrodeoxygenation of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran over Heterogeneous Iron Catalysts |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-18T10%3A14%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Selective%20Hydrodeoxygenation%20of%205%E2%80%90Hydroxymethylfurfural%20to%202,5%E2%80%90Dimethylfuran%20over%20Heterogeneous%20Iron%20Catalysts&rft.jtitle=ChemSusChem&rft.au=Li,%20Jiang&rft.date=2017-04-10&rft.volume=10&rft.issue=7&rft.spage=1436&rft.epage=1447&rft.pages=1436-1447&rft.issn=1864-5631&rft.eissn=1864-564X&rft_id=info:doi/10.1002/cssc.201700105&rft_dat=%3Cproquest_cross%3E4321599271%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1886197587&rft_id=info:pmid/28160439&rfr_iscdi=true |