Diastereomerically Pure Heterodi- and Heterotetrametallic (Pd and Pt) Compounds: A Study of the Effect Induced by the Binding Mode of a Ferrocene-Containing Ligand on Their Electrochemical Properties

The reaction of (1S,2R)‐[(η5‐C5H5)Fe{(η5‐C5H4)‐CH=N‐CH(Me)‐CH(OH)(C6H5)}] (1) with Na2[PdCl4] in the presence of Na(OAc)·3H2O produced three diastereomerically pure tetrametallic cyclopalladated complexes (6bI–6bIII). In two of them (6bI and 6bII), the imine 1 adopts the [C(sp2,ferrocene),N]– mode o...

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Veröffentlicht in:	European journal of inorganic chemistry 2014-01, Vol.2014 (1), p.213-220
Hauptverfasser:	Talancón, Daniel, López, Concepción, Font-Bardía, Mercè, Calvet, Teresa, Roubeau, Olivier
Format:	Artikel
Sprache:	eng
Schlagworte:	Binding Chirality Coordination modes Cyclometallated compounds Electrochemical analysis Electrochemistry Imines Ligands Palladium Platinum Sandwich complexes
Online-Zugang:	Volltext
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