The C–OH/P–H dehydrative cross-coupling for the construction of the P–C bond under metal-free conditions

Herein, we report an atom-economical and environmentally benign approach for P-C bond construction via C-OH/P-H dehydrative cross-coupling reaction. This reaction was carried out under metal-free conditions, proceeds in the absence of any solvent and delivered allylic phosphorus compounds in high yi...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2017, Vol.19 (9), p.2135-2139
Hauptverfasser: Xie, Peizhong, Wang, Jinyu, Fan, Jing, Liu, Yanan, Wo, Xiangyang, Loh, Teck-Peng
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container_title Green chemistry : an international journal and green chemistry resource : GC
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creator Xie, Peizhong
Wang, Jinyu
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description Herein, we report an atom-economical and environmentally benign approach for P-C bond construction via C-OH/P-H dehydrative cross-coupling reaction. This reaction was carried out under metal-free conditions, proceeds in the absence of any solvent and delivered allylic phosphorus compounds in high yields with wide functional group tolerance.
doi_str_mv 10.1039/c7gc00882a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chemical bonds
Chemical reactions
Cross coupling
Dehydration
Functional groups
Phosphorus compounds
Solvents
Tolerances
title The C–OH/P–H dehydrative cross-coupling for the construction of the P–C bond under metal-free conditions
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