Switchable regioselectivity in amine-catalysed asymmetric cycloadditions

Building small-molecule libraries with structural and stereogenic diversity plays an important role in drug discovery. The development of switchable intermolecular cycloaddition reactions from identical substrates in different regioselective fashions would provide an attractive protocol. However, th...

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Veröffentlicht in:	Nature chemistry 2017-06, Vol.9 (6), p.590-594
Hauptverfasser:	Zhou, Zhi, Wang, Zhou-Xiang, Zhou, Yuan-Chun, Xiao, Wei, Ouyang, Qin, Du, Wei, Chen, Ying-Chun
Format:	Artikel
Sprache:	eng
Schlagworte:	119/118 140/131 140/58 639/638/403/933 639/638/403/935 Alkylidene Amines Analytical Chemistry Asymmetry Biochemistry Catalysis Chemical bonds Chemistry Chemistry/Food Science Cycloaddition Drug discovery Inorganic Chemistry Libraries Organic Chemistry Physical Chemistry Regioselectivity Stereoselectivity Substrates Thiols
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