Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads

Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads

Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV–vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calcul...

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Veröffentlicht in:Inorganic chemistry 2017-06, Vol.56 (11), p.6039-6043
Hauptverfasser: Kwak, Sang Woo, Choi, Byung Hoon, Lee, Ji Hye, Hwang, Hyonseok, Lee, Junseong, Kwon, Hyoshik, Chung, Yongseog, Lee, Kang Mun, Park, Myung Hwan
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Sprache:eng
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Zusammenfassung:Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV–vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calculation and fluoride titration results further supported these intramolecular energy-transfer features.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.7b00768