Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(i)
The synthesis of novel bis(trithio)phosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(i) reagent [P dppe][Br] in good yields under ambient conditions. These bis(trithio)phosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and...
Gespeichert in:
| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2017-08, Vol.46 (30), p.9769-9776 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 9776 |
|---|---|
| container_issue | 30 |
| container_start_page | 9769 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 46 |
| creator | Kosnik, Stephanie C Nascimento, Maxemilian C Rawson, Jeremy M Macdonald, Charles L B |
| description | The synthesis of novel bis(trithio)phosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(i) reagent [P
dppe][Br] in good yields under ambient conditions. These bis(trithio)phosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and multinuclear NMR and a mechanism is proposed for the formation of these molecules. In contrast, the related reaction with diphenyldisulfide produces a mononuclear tris(phenylthio)phosphine. |
| doi_str_mv | 10.1039/c7dt01345k |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1901310813</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1901310813</sourcerecordid><originalsourceid>FETCH-LOGICAL-c323t-97e6152525281289574e4eee919054a4edc48c0c6205914bc3d008791e374a313</originalsourceid><addsrcrecordid>eNo9kD1PwzAQQC0EoqWw8ANQxhYp4LOdOh5R-aYSA2WOEueiGNo42A6i_56UluqGu-Hp6fQIOQd6BZSray3LQIGL5POADEFIGSvGxeH-ZtMBOfH-g1LGaMKOyYClCacU6JA8v62bUKM3PrJVVBg_Ds6E2thJW1vf1qZBHxXryP6YMg_mG6Pg8sZX6Db8lrGu82MzOSVHVb70eLbbI_J-f7eYPcbz14en2c081pzxECuJU0jYZlJgqUqkQIGIChRNRC6w1CLVVE_7XxWIQvOS0lQqQC5FzoGPyHjrbZ396tCHbGW8xuUyb9B2Pus9wIGmwHv0cotqZ713WGWtM6vcrTOg2aZdNpO3i792Lz18sfN2xQrLPfofi_8Cs8NoQw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1901310813</pqid></control><display><type>article</type><title>Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(i)</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Kosnik, Stephanie C ; Nascimento, Maxemilian C ; Rawson, Jeremy M ; Macdonald, Charles L B</creator><creatorcontrib>Kosnik, Stephanie C ; Nascimento, Maxemilian C ; Rawson, Jeremy M ; Macdonald, Charles L B</creatorcontrib><description>The synthesis of novel bis(trithio)phosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(i) reagent [P
dppe][Br] in good yields under ambient conditions. These bis(trithio)phosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and multinuclear NMR and a mechanism is proposed for the formation of these molecules. In contrast, the related reaction with diphenyldisulfide produces a mononuclear tris(phenylthio)phosphine.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c7dt01345k</identifier><identifier>PMID: 28530010</identifier><language>eng</language><publisher>England</publisher><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2017-08, Vol.46 (30), p.9769-9776</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c323t-97e6152525281289574e4eee919054a4edc48c0c6205914bc3d008791e374a313</citedby><cites>FETCH-LOGICAL-c323t-97e6152525281289574e4eee919054a4edc48c0c6205914bc3d008791e374a313</cites><orcidid>0000-0002-0574-1524 ; 0000-0003-0480-5386</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28530010$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kosnik, Stephanie C</creatorcontrib><creatorcontrib>Nascimento, Maxemilian C</creatorcontrib><creatorcontrib>Rawson, Jeremy M</creatorcontrib><creatorcontrib>Macdonald, Charles L B</creatorcontrib><title>Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(i)</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>The synthesis of novel bis(trithio)phosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(i) reagent [P
dppe][Br] in good yields under ambient conditions. These bis(trithio)phosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and multinuclear NMR and a mechanism is proposed for the formation of these molecules. In contrast, the related reaction with diphenyldisulfide produces a mononuclear tris(phenylthio)phosphine.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo9kD1PwzAQQC0EoqWw8ANQxhYp4LOdOh5R-aYSA2WOEueiGNo42A6i_56UluqGu-Hp6fQIOQd6BZSray3LQIGL5POADEFIGSvGxeH-ZtMBOfH-g1LGaMKOyYClCacU6JA8v62bUKM3PrJVVBg_Ds6E2thJW1vf1qZBHxXryP6YMg_mG6Pg8sZX6Db8lrGu82MzOSVHVb70eLbbI_J-f7eYPcbz14en2c081pzxECuJU0jYZlJgqUqkQIGIChRNRC6w1CLVVE_7XxWIQvOS0lQqQC5FzoGPyHjrbZ396tCHbGW8xuUyb9B2Pus9wIGmwHv0cotqZ713WGWtM6vcrTOg2aZdNpO3i792Lz18sfN2xQrLPfofi_8Cs8NoQw</recordid><startdate>20170814</startdate><enddate>20170814</enddate><creator>Kosnik, Stephanie C</creator><creator>Nascimento, Maxemilian C</creator><creator>Rawson, Jeremy M</creator><creator>Macdonald, Charles L B</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0574-1524</orcidid><orcidid>https://orcid.org/0000-0003-0480-5386</orcidid></search><sort><creationdate>20170814</creationdate><title>Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(i)</title><author>Kosnik, Stephanie C ; Nascimento, Maxemilian C ; Rawson, Jeremy M ; Macdonald, Charles L B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c323t-97e6152525281289574e4eee919054a4edc48c0c6205914bc3d008791e374a313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kosnik, Stephanie C</creatorcontrib><creatorcontrib>Nascimento, Maxemilian C</creatorcontrib><creatorcontrib>Rawson, Jeremy M</creatorcontrib><creatorcontrib>Macdonald, Charles L B</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kosnik, Stephanie C</au><au>Nascimento, Maxemilian C</au><au>Rawson, Jeremy M</au><au>Macdonald, Charles L B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(i)</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2017-08-14</date><risdate>2017</risdate><volume>46</volume><issue>30</issue><spage>9769</spage><epage>9776</epage><pages>9769-9776</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The synthesis of novel bis(trithio)phosphines is achieved by oxidative addition of tetrathiocins to the phosphorus(i) reagent [P
dppe][Br] in good yields under ambient conditions. These bis(trithio)phosphines and the related intermediate diphosphine species are characterized by X-ray diffraction and multinuclear NMR and a mechanism is proposed for the formation of these molecules. In contrast, the related reaction with diphenyldisulfide produces a mononuclear tris(phenylthio)phosphine.</abstract><cop>England</cop><pmid>28530010</pmid><doi>10.1039/c7dt01345k</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-0574-1524</orcidid><orcidid>https://orcid.org/0000-0003-0480-5386</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2017-08, Vol.46 (30), p.9769-9776 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1901310813 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Synthesis of bis(trithio)phosphines by oxidative transfer of phosphorus(i) |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T05%3A57%3A54IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20of%20bis(trithio)phosphines%20by%20oxidative%20transfer%20of%20phosphorus(i)&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Kosnik,%20Stephanie%20C&rft.date=2017-08-14&rft.volume=46&rft.issue=30&rft.spage=9769&rft.epage=9776&rft.pages=9769-9776&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/c7dt01345k&rft_dat=%3Cproquest_cross%3E1901310813%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1901310813&rft_id=info:pmid/28530010&rfr_iscdi=true |