[60]Fullerene‐Based Macrocycle Ligands
Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 th...
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| Veröffentlicht in: | Chemistry : a European journal 2017-08, Vol.23 (44), p.10485-10490 |
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| container_title | Chemistry : a European journal |
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| creator | Li, Yanbang Gan, Liangbing |
| description | Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO–LUMO gaps. The synthesis of these ligands is a challenging task. Nevertheless important progresses have been reported. This concept article focuses on the structures of possible C60‐based macrocycle ligands and related synthetic results.
Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO–LUMO gaps. |
| doi_str_mv | 10.1002/chem.201701526 |
| format | Article |
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Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO–LUMO gaps.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201701526</identifier><identifier>PMID: 28504413</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Buckminsterfullerene ; Chemistry ; curved π-systems ; fullerene ; Fullerenes ; heterocycle ; Ligands ; macrocycle ; Molecular orbitals ; Vacancies</subject><ispartof>Chemistry : a European journal, 2017-08, Vol.23 (44), p.10485-10490</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4766-d9d91ec1ee82baa355547c884ea055c91646585b139113deaf842e67f97fb7013</citedby><cites>FETCH-LOGICAL-c4766-d9d91ec1ee82baa355547c884ea055c91646585b139113deaf842e67f97fb7013</cites><orcidid>0000-0001-6646-3452</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201701526$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201701526$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28504413$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Yanbang</creatorcontrib><creatorcontrib>Gan, Liangbing</creatorcontrib><title>[60]Fullerene‐Based Macrocycle Ligands</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO–LUMO gaps. The synthesis of these ligands is a challenging task. Nevertheless important progresses have been reported. This concept article focuses on the structures of possible C60‐based macrocycle ligands and related synthetic results.
Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO–LUMO gaps.</description><subject>Buckminsterfullerene</subject><subject>Chemistry</subject><subject>curved π-systems</subject><subject>fullerene</subject><subject>Fullerenes</subject><subject>heterocycle</subject><subject>Ligands</subject><subject>macrocycle</subject><subject>Molecular orbitals</subject><subject>Vacancies</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkL1OwzAUhS0EoqWwMqJKLF1SfP0Xe4SqpUhFLDAhZDnODaRKmhIToW48As_Ik5CqpUgsTGf57qd7DiGnQIdAKbvwL1gOGYWYgmRqj3TbgIjHSu6TLjUijpTkpkOOQphTSo3i_JB0mJZUCOBdMnhU9GnSFAXWuMCvj88rFzDt3zpfV37lC-zP8me3SMMxOchcEfBkmz3yMBnfj6bR7O76ZnQ5i7yIlYpSkxpAD4iaJc5xKaWIvdYCHZXSG1BCSS0T4AaAp-gyLRiqODNxlrQleI8MNt5lXb02GN5smQePReEWWDXBgjYGKNd6jZ7_QedVUy_a7ywYJjWVTKqWGm6otlEINWZ2Weelq1cWqF1vaNcb2t2G7cHZVtskJaY7_Ge0FjAb4D0vcPWPzo6m49tf-TcROXs_</recordid><startdate>20170804</startdate><enddate>20170804</enddate><creator>Li, Yanbang</creator><creator>Gan, Liangbing</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6646-3452</orcidid></search><sort><creationdate>20170804</creationdate><title>[60]Fullerene‐Based Macrocycle Ligands</title><author>Li, Yanbang ; Gan, Liangbing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4766-d9d91ec1ee82baa355547c884ea055c91646585b139113deaf842e67f97fb7013</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Buckminsterfullerene</topic><topic>Chemistry</topic><topic>curved π-systems</topic><topic>fullerene</topic><topic>Fullerenes</topic><topic>heterocycle</topic><topic>Ligands</topic><topic>macrocycle</topic><topic>Molecular orbitals</topic><topic>Vacancies</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Yanbang</creatorcontrib><creatorcontrib>Gan, Liangbing</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Yanbang</au><au>Gan, Liangbing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[60]Fullerene‐Based Macrocycle Ligands</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2017-08-04</date><risdate>2017</risdate><volume>23</volume><issue>44</issue><spage>10485</spage><epage>10490</epage><pages>10485-10490</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO–LUMO gaps. The synthesis of these ligands is a challenging task. Nevertheless important progresses have been reported. This concept article focuses on the structures of possible C60‐based macrocycle ligands and related synthetic results.
Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage‐shaped backbone. Theoretical calculations indicate that such C60‐based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO–LUMO gaps.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>28504413</pmid><doi>10.1002/chem.201701526</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-6646-3452</orcidid></addata></record> |
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| ispartof | Chemistry : a European journal, 2017-08, Vol.23 (44), p.10485-10490 |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Buckminsterfullerene Chemistry curved π-systems fullerene Fullerenes heterocycle Ligands macrocycle Molecular orbitals Vacancies |
| title | [60]Fullerene‐Based Macrocycle Ligands |
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