Modeling Fungal Melanin Buildup: Biomimetic Polymerization of 1,8‐Dihydroxynaphthalene Mapped by Mass Spectrometry

Due to the emerging biomedical relevance and technological potential of fungal melanins, and prompted by the virtual lack of information about their structural arrangement, an optimized synthetic protocol has been devised for a potential structural model of Ascomyces allomelanin through enzyme‐catal...

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Veröffentlicht in:	Chemistry : a European journal 2017-06, Vol.23 (33), p.8092-8098
Hauptverfasser:	Cecchini, Martina Maya, Reale, Samantha, Manini, Paola, d'Ischia, Marco, De Angelis, Francesco
Format:	Artikel
Sprache:	eng
Schlagworte:	1,8-dihydroxynaphthalene Biocatalysis Biomedical materials Biomimetic materials Biomimetic Materials - chemistry Biomimetic Materials - metabolism biomimetic polymerization Biomimetics Chains (polymeric) Chemical synthesis Chemistry Chromatography, High Pressure Liquid Coupling (molecular) Functional anatomy fungal melanins Fungal Proteins - chemistry Fungal Proteins - metabolism Fungi Fungi - metabolism Horseradish Peroxidase - metabolism Ionization Ions Liquid chromatography Mass spectrometry Mass spectroscopy Melanin Melanins - chemistry Melanins - metabolism Modelling Naphthalene Naphthols - chemistry Oligomers Oxidation-Reduction Polymerization Polymers Scientific imaging Spectrometry, Mass, Electrospray Ionization structural modeling Tandem Mass Spectrometry
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