Laccase-catalyzed synthesis of conducting polyaniline
Laccase isolated from Coriolus hirsutus was first used in the synthesis of water-soluble conducting polyaniline. The laccase-catalyzed polymerization of aniline was performed in the presence of sulfonated polystyrene (SPS) as a template. Laccase shows remarkable advantages in the synthesis of conduc...
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| Veröffentlicht in: | Enzyme and microbial technology 2003-10, Vol.33 (5), p.556-564 |
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| container_title | Enzyme and microbial technology |
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| creator | Karamyshev, Alexey V Shleev, Sergey V Koroleva, Olga V Yaropolov, Alexander I Sakharov, Ivan Yu |
| description | Laccase isolated from
Coriolus hirsutus was first used in the synthesis of water-soluble conducting polyaniline. The laccase-catalyzed polymerization of aniline was performed in the presence of sulfonated polystyrene (SPS) as a template. Laccase shows remarkable advantages in the synthesis of conducting polyaniline compared to the commonly used horseradish peroxidase due to its high activity and stability under acidic conditions. The characterization of the polyelectrolyte complex of polyaniline and SPS has been carried out using UV-Vis and FTIR spectroscopy. Cyclic voltammetry and dc conductivity measurements confirmed that electroactive polyaniline was synthesized by the laccase-catalyzed polymerization of aniline. |
| doi_str_mv | 10.1016/S0141-0229(03)00163-7 |
| format | Article |
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Coriolus hirsutus was first used in the synthesis of water-soluble conducting polyaniline. The laccase-catalyzed polymerization of aniline was performed in the presence of sulfonated polystyrene (SPS) as a template. Laccase shows remarkable advantages in the synthesis of conducting polyaniline compared to the commonly used horseradish peroxidase due to its high activity and stability under acidic conditions. The characterization of the polyelectrolyte complex of polyaniline and SPS has been carried out using UV-Vis and FTIR spectroscopy. Cyclic voltammetry and dc conductivity measurements confirmed that electroactive polyaniline was synthesized by the laccase-catalyzed polymerization of aniline.</description><identifier>ISSN: 0141-0229</identifier><identifier>EISSN: 1879-0909</identifier><identifier>DOI: 10.1016/S0141-0229(03)00163-7</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Coriolus hirsutus ; Laccase ; Polyaniline ; polystyrene</subject><ispartof>Enzyme and microbial technology, 2003-10, Vol.33 (5), p.556-564</ispartof><rights>2003 Elsevier Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c441t-409fbff4aba0b1c21370c97df489f1cb12d68f5ea3e81785a497574535bcecf13</citedby><cites>FETCH-LOGICAL-c441t-409fbff4aba0b1c21370c97df489f1cb12d68f5ea3e81785a497574535bcecf13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0141-0229(03)00163-7$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3549,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Karamyshev, Alexey V</creatorcontrib><creatorcontrib>Shleev, Sergey V</creatorcontrib><creatorcontrib>Koroleva, Olga V</creatorcontrib><creatorcontrib>Yaropolov, Alexander I</creatorcontrib><creatorcontrib>Sakharov, Ivan Yu</creatorcontrib><title>Laccase-catalyzed synthesis of conducting polyaniline</title><title>Enzyme and microbial technology</title><description>Laccase isolated from
Coriolus hirsutus was first used in the synthesis of water-soluble conducting polyaniline. The laccase-catalyzed polymerization of aniline was performed in the presence of sulfonated polystyrene (SPS) as a template. Laccase shows remarkable advantages in the synthesis of conducting polyaniline compared to the commonly used horseradish peroxidase due to its high activity and stability under acidic conditions. The characterization of the polyelectrolyte complex of polyaniline and SPS has been carried out using UV-Vis and FTIR spectroscopy. Cyclic voltammetry and dc conductivity measurements confirmed that electroactive polyaniline was synthesized by the laccase-catalyzed polymerization of aniline.</description><subject>Coriolus hirsutus</subject><subject>Laccase</subject><subject>Polyaniline</subject><subject>polystyrene</subject><issn>0141-0229</issn><issn>1879-0909</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAURYMoOI7-BKEr0UU1r0kmzUpk8AsGXKjrkL6-aKTTjklHqL_ezoy4dfXgcu6Fdxg7BX4JHGZXzxwk5LwozDkXF3yMRK732ARKbXJuuNlnkz_kkB2l9MFHSko-YWrhEF2iHF3vmuGb6iwNbf9OKaSs8xl2bb3GPrRv2aprBteGJrR0zA68axKd_N4pe727fZk_5Iun-8f5zSJHKaHPJTe-8l66yvEKsAChORpde1kaD1hBUc9Kr8gJKkGXykmjlZZKqAoJPYgpO9vtrmL3uabU22VISE3jWurWyUJpFJRKjKDagRi7lCJ5u4ph6eJggduNJLuVZDcGLBd2K8nqsXe969H4xVegaBMGapHqEAl7W3fhn4Uf0PBulg</recordid><startdate>20031001</startdate><enddate>20031001</enddate><creator>Karamyshev, Alexey V</creator><creator>Shleev, Sergey V</creator><creator>Koroleva, Olga V</creator><creator>Yaropolov, Alexander I</creator><creator>Sakharov, Ivan Yu</creator><general>Elsevier Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7T7</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20031001</creationdate><title>Laccase-catalyzed synthesis of conducting polyaniline</title><author>Karamyshev, Alexey V ; Shleev, Sergey V ; Koroleva, Olga V ; Yaropolov, Alexander I ; Sakharov, Ivan Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c441t-409fbff4aba0b1c21370c97df489f1cb12d68f5ea3e81785a497574535bcecf13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Coriolus hirsutus</topic><topic>Laccase</topic><topic>Polyaniline</topic><topic>polystyrene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karamyshev, Alexey V</creatorcontrib><creatorcontrib>Shleev, Sergey V</creatorcontrib><creatorcontrib>Koroleva, Olga V</creatorcontrib><creatorcontrib>Yaropolov, Alexander I</creatorcontrib><creatorcontrib>Sakharov, Ivan Yu</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Enzyme and microbial technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karamyshev, Alexey V</au><au>Shleev, Sergey V</au><au>Koroleva, Olga V</au><au>Yaropolov, Alexander I</au><au>Sakharov, Ivan Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Laccase-catalyzed synthesis of conducting polyaniline</atitle><jtitle>Enzyme and microbial technology</jtitle><date>2003-10-01</date><risdate>2003</risdate><volume>33</volume><issue>5</issue><spage>556</spage><epage>564</epage><pages>556-564</pages><issn>0141-0229</issn><eissn>1879-0909</eissn><abstract>Laccase isolated from
Coriolus hirsutus was first used in the synthesis of water-soluble conducting polyaniline. The laccase-catalyzed polymerization of aniline was performed in the presence of sulfonated polystyrene (SPS) as a template. Laccase shows remarkable advantages in the synthesis of conducting polyaniline compared to the commonly used horseradish peroxidase due to its high activity and stability under acidic conditions. The characterization of the polyelectrolyte complex of polyaniline and SPS has been carried out using UV-Vis and FTIR spectroscopy. Cyclic voltammetry and dc conductivity measurements confirmed that electroactive polyaniline was synthesized by the laccase-catalyzed polymerization of aniline.</abstract><pub>Elsevier Inc</pub><doi>10.1016/S0141-0229(03)00163-7</doi><tpages>9</tpages></addata></record> |
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| ispartof | Enzyme and microbial technology, 2003-10, Vol.33 (5), p.556-564 |
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| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Coriolus hirsutus Laccase Polyaniline polystyrene |
| title | Laccase-catalyzed synthesis of conducting polyaniline |
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