The bifunctional catalytic role of water clusters in the formation of acid rain
State-of-the-art chemical bonding analyses show that water clusters have a bifunctional catalytic role in the formation of H SO in acid rain. The embedded H O monomers mitigate the change in the chemical bonding scenario of the rate-limiting step, reducing thereby the corresponding activation energy...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2017-03, Vol.53 (25), p.3516-3519 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Romero-Montalvo, Eduardo Guevara-Vela, José Manuel Vallejo Narváez, Wilmer Esteban Costales, Aurora Pendás, Ángel Martín Hernández-Rodríguez, Marcos Rocha-Rinza, Tomás |
| description | State-of-the-art chemical bonding analyses show that water clusters have a bifunctional catalytic role in the formation of H
SO
in acid rain. The embedded H
O monomers mitigate the change in the chemical bonding scenario of the rate-limiting step, reducing thereby the corresponding activation energy in accordance with Hammond's postulate. We expect that the insights given herein will prove useful in the elucidation of the catalytic mechanisms of water in inorganic and organic aqueous chemistry. |
| doi_str_mv | 10.1039/c6cc09616f |
| format | Article |
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SO
in acid rain. The embedded H
O monomers mitigate the change in the chemical bonding scenario of the rate-limiting step, reducing thereby the corresponding activation energy in accordance with Hammond's postulate. We expect that the insights given herein will prove useful in the elucidation of the catalytic mechanisms of water in inorganic and organic aqueous chemistry.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/c6cc09616f</identifier><identifier>PMID: 28205659</identifier><language>eng</language><publisher>England</publisher><subject>Acid rain ; Catalysis ; Catalysts ; Chemical bonds ; Clusters ; Formations ; Monomers ; State of the art</subject><ispartof>Chemical communications (Cambridge, England), 2017-03, Vol.53 (25), p.3516-3519</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c320t-86d06c6bf0ceee3d6e9db2e781cdf396138a25da4a76541742a5088cf6d162d63</citedby><cites>FETCH-LOGICAL-c320t-86d06c6bf0ceee3d6e9db2e781cdf396138a25da4a76541742a5088cf6d162d63</cites><orcidid>0000-0003-1650-4150 ; 0000-0002-4471-4000</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27906,27907</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28205659$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Romero-Montalvo, Eduardo</creatorcontrib><creatorcontrib>Guevara-Vela, José Manuel</creatorcontrib><creatorcontrib>Vallejo Narváez, Wilmer Esteban</creatorcontrib><creatorcontrib>Costales, Aurora</creatorcontrib><creatorcontrib>Pendás, Ángel Martín</creatorcontrib><creatorcontrib>Hernández-Rodríguez, Marcos</creatorcontrib><creatorcontrib>Rocha-Rinza, Tomás</creatorcontrib><title>The bifunctional catalytic role of water clusters in the formation of acid rain</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>State-of-the-art chemical bonding analyses show that water clusters have a bifunctional catalytic role in the formation of H
SO
in acid rain. The embedded H
O monomers mitigate the change in the chemical bonding scenario of the rate-limiting step, reducing thereby the corresponding activation energy in accordance with Hammond's postulate. We expect that the insights given herein will prove useful in the elucidation of the catalytic mechanisms of water in inorganic and organic aqueous chemistry.</description><subject>Acid rain</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical bonds</subject><subject>Clusters</subject><subject>Formations</subject><subject>Monomers</subject><subject>State of the art</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNkEtLxDAUhYMozji68QdIliJUk6a5TZZSZlQYmM0I7kqaB0b6GJMWmX9v64yuvZtzF985cA5C15TcU8LkgwatiQQK7gTNKYMs4Zl4O51-LpOcZXyGLmL8IONRLs7RLBUp4cDlHG227xZX3g2t7n3Xqhpr1at633uNQ1db3Dn8pXobsK6HOGrEvsX9aHJdaNTkmRClvcFB-fYSnTlVR3t11AV6XS23xXOy3jy9FI_rRLOU9IkAQ0BD5Yi21jIDVpoqtbmg2jg2dmFCpdyoTOXAM5pnqeJECO3AUEgNsAW6PeTuQvc52NiXjY_a1rVqbTfEkgrJJKU5o_9AQRLJOCcjendAdehiDNaVu-AbFfYlJeW0dVlAUfxsvRrhm2PuUDXW_KG_47JvU8l5HQ</recordid><startdate>20170323</startdate><enddate>20170323</enddate><creator>Romero-Montalvo, Eduardo</creator><creator>Guevara-Vela, José Manuel</creator><creator>Vallejo Narváez, Wilmer Esteban</creator><creator>Costales, Aurora</creator><creator>Pendás, Ángel Martín</creator><creator>Hernández-Rodríguez, Marcos</creator><creator>Rocha-Rinza, Tomás</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-1650-4150</orcidid><orcidid>https://orcid.org/0000-0002-4471-4000</orcidid></search><sort><creationdate>20170323</creationdate><title>The bifunctional catalytic role of water clusters in the formation of acid rain</title><author>Romero-Montalvo, Eduardo ; Guevara-Vela, José Manuel ; Vallejo Narváez, Wilmer Esteban ; Costales, Aurora ; Pendás, Ángel Martín ; Hernández-Rodríguez, Marcos ; Rocha-Rinza, Tomás</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-86d06c6bf0ceee3d6e9db2e781cdf396138a25da4a76541742a5088cf6d162d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Acid rain</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical bonds</topic><topic>Clusters</topic><topic>Formations</topic><topic>Monomers</topic><topic>State of the art</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Romero-Montalvo, Eduardo</creatorcontrib><creatorcontrib>Guevara-Vela, José Manuel</creatorcontrib><creatorcontrib>Vallejo Narváez, Wilmer Esteban</creatorcontrib><creatorcontrib>Costales, Aurora</creatorcontrib><creatorcontrib>Pendás, Ángel Martín</creatorcontrib><creatorcontrib>Hernández-Rodríguez, Marcos</creatorcontrib><creatorcontrib>Rocha-Rinza, Tomás</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Romero-Montalvo, Eduardo</au><au>Guevara-Vela, José Manuel</au><au>Vallejo Narváez, Wilmer Esteban</au><au>Costales, Aurora</au><au>Pendás, Ángel Martín</au><au>Hernández-Rodríguez, Marcos</au><au>Rocha-Rinza, Tomás</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The bifunctional catalytic role of water clusters in the formation of acid rain</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2017-03-23</date><risdate>2017</risdate><volume>53</volume><issue>25</issue><spage>3516</spage><epage>3519</epage><pages>3516-3519</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>State-of-the-art chemical bonding analyses show that water clusters have a bifunctional catalytic role in the formation of H
SO
in acid rain. The embedded H
O monomers mitigate the change in the chemical bonding scenario of the rate-limiting step, reducing thereby the corresponding activation energy in accordance with Hammond's postulate. We expect that the insights given herein will prove useful in the elucidation of the catalytic mechanisms of water in inorganic and organic aqueous chemistry.</abstract><cop>England</cop><pmid>28205659</pmid><doi>10.1039/c6cc09616f</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-1650-4150</orcidid><orcidid>https://orcid.org/0000-0002-4471-4000</orcidid></addata></record> |
| fulltext | fulltext |
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| ispartof | Chemical communications (Cambridge, England), 2017-03, Vol.53 (25), p.3516-3519 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1893911731 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Acid rain Catalysis Catalysts Chemical bonds Clusters Formations Monomers State of the art |
| title | The bifunctional catalytic role of water clusters in the formation of acid rain |
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